Repository for Oil and Gas Energy Research (ROGER)

Abstract:
Membrane distillation (MD), often integrated with crystallization (MDC), is an attractive treatment option for shale gas produced water (SGPW) because of its ability to handle high salinity as well as the inherent geothermal heat available to this process. To evaluate the feasibility of applying MD process for SGPW treatment, membrane fouling and wetting, which are barrier to its practical application, were systematically examined by varying organic and inorganic constituents, simulating the SGPW from Marcellus shale (USA). The liquid entry pressure (LEP) was first measured to predict the possibility of wetting by the chemical constituents of SGPW, and then a series of lab-scale MD and MDC experiments were performed to elucidate membrane wetting mechanisms. The results revealed that membrane wetting became more pronounced in the presence of oil and grease. The inorganic scaling induced by multivalent ions, such as barium and calcium in SGPW, also enhanced membrane wettability and led to poor permeate water quality. By integrating with crystallization, scalant loading was reduced properly and thus membrane wetting was mitigated effectively. As a result, adopting this MDC process increased total recovery up to 62.5%. Our experimental observations demonstrated that MD could be sustainably operated for SGPW treatment through optimized crystallization for scaling removal as well as effective pre-treatment for organic removal.

Abstract:
We provide a critical review of existing research and information regarding the sources of risk associated with on-site shale gas and tight oil wastewater storage in the United States, the gaps that exist in knowledge regarding these risks, policy and technology options for addressing the risks, and the relative merits of those options. Specifically, we (a) identify the potential risks to human and ecological health associated with on-site storage of shale gas and tight oil wastewater via a literature survey and analysis of data on wastewater spills and regulatory violations, (b) provide a detailed description of government regulations or industry actions that may mitigate these risks to human and ecological health, and (c) provide a critical review of this information to help generate progress toward concrete action to make shale gas and tight oil development more sustainable and more acceptable to a skeptical public, while keeping costs down.

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The logistical issues surrounding the timing and transport of flowback generated by each shale gas well to the next is a big challenge. Due to more and more flowback being stored temporarily near the shale gas well and reused in the shale gas development, both transportation cost and storage cost are the heavy burden for the developers. This research proposed a theoretical cost optimization model to get the optimal flowback distribution solution for regional multi shale gas wells in a holistic perspective. Then, we used some empirical data of Marcellus Shale to do the empirical study. In addition, we compared the optimal flowback distribution solution by considering both the transportation cost and storage cost with the flowback distribution solution which only minimized the transportation cost or only minimized the storage cost.

Abstract:
Over the past 60 years, road deicers (i.e. road salt) have been applied to roadways in high latitudes to improve road conditions in winter weather. However, the dissolution of road deicers in highway runoff creates waters with high concentrations of sodium, which can mobilize soil metals via soil cation-exchange reactions. While several studies have detailed the interactions of road salt-rich solutions and surface and ground waters, less attention has been given to how local hydrologic flowpaths can impact the delivery of these solutions to near-road soils. Between 2013 and 2014, soil water samples were collected from a roadside transect of lysimeter nests in Pittsburgh, Pennsylvania (USA). Soil water samples were analysed for metal concentrations and resulting data used to examine cation dynamics. While patterns in soil water calcium and magnesium concentrations follow patterns in soil water sodium concentrations, additional processes influence patterns in soil water potassium concentrations. Specifically, we observe the highest calcium and magnesium concentrations in the deepest lysimeters, suggesting divalent cations are mobilized to, and potentially accumulate in, deeper soil horizons. In contrast, soil water potassium concentrations do not follow this pattern. Additionally, in all examined elements (Ca, Mg, K, Na, and Cl), the timing of concentration peaks appears be influenced by a combination of both distance from the roadside and sampling depth. These relationships not only suggest that multiple soil water flowpaths interact with our study transect but also confirm that road salt plumes persist and migrate following the road salting season. Characterizing the interactions of sodium-rich solutions and roadside soil cation pools clarifies our understanding of metal dynamics in the roadside environment. A deeper understanding of these processes is necessary to effectively restore and manage watersheds as high total dissolved solid solutions (e.g. road deicing melt, unconventional natural gas brines, and marginal irrigation water) continue to influence hydrological systems. Copyright (C) 2016 John Wiley & Sons, Ltd.

Abstract:
Hydraulic fracturing consumes billions of gallons of water each year to extract oil and natural gas from the ground. The resulting wastewater contains sand, salts, metals, gel, diluted acid, and other unknown proppants, and does not meet the EPA standards for environmental release. With the goal of treating the hydraulic fracturing water to meet the highest possible EPA standards for water quality, a benchtop water purification process was designed, built, and tested. The treatment process consisted of an activated charcoal adsorption column filter, a reverse osmosis membrane and ion exchange columns. Produced water from Eagle Ford Shale was pumped through the system and samples were collected before and after each unit operation. The water, treated with this system, was pumped through the system a second time; samples were collected and analyzed using the same methodology from the first iteration to analyze the potential benefits of a second iteration. In order to assess the effectiveness of each unit operation and iteration in the wastewater treatment system, a series of experiments were designed to monitor the flow ratio, metal & salt content, pH, and change in organic content. Inductively coupled plasma optical emission spectrometry was implemented as a means to measure the metal and salt content present in the water at various purification steps. The produced waters initial metal content was determined to be 184.45 ppm, and the initial salt content was determined to be 2,262.26 ppm. After the first iteration of treatment, the final metal and salt contents were determined to be 0.32 ppm and 1.39 ppm respectively. Gas chromatography was used to monitor organic content. The total organic content of the produced water was reduced by 83.5% by the treatment process. The initial pH of the produced water was 4.25, and after the first iteration of treatment, the final pH was 5.31. The produced water treated in our process in a single iteration met the EPA standards for metal and salt content for potable water; however the pH is at the lower end of the standard. The second iteration analysis showed that the pH of the twice treated water was raised to acceptable levels for potable water, however the concentration of the other pollutants changed negligibly. Based on the average national price for electricity, a treatment system that operated for 10 years would cost $1.68 per day, including the capital costs. The performance analysis indicated that the treatment system has commercial applications for home use in areas with groundwater affected by hydraulic fracturing wastewater.

Abstract:
Shale gas produced water is a hypersaline wastewater that is generated during the shale gas development process called as a hydraulic fracturing. The produced water contains many substances including inorganic salts, organic compounds, and particulates. The treatment process of the produced water is mainly composed of four parts: oil and water separation, removal of suspended solids, removal of organics, and salts removal. This study focuses on the total dissolved salts removal through applying three different desalination techniques - membrane distillation (MD), reverse osmosis (RO), and evaporative crystallization (EC). The experiments were conducted using synthetic shale gas produced water to understand the changes of chemical properties in permeate and concentrate. In the permeate solution, MD and EC showed more than 99% of salts removal efficiency for all ions, but RO showed relatively low efficiency. In the concentrate solution, the concentrations of all ions varied according to the type of ions and applied treatment methods.

Abstract:
The produced water, which could be a complex mixture of different organic and inorganic compounds (mostly salts, minerals and oils) is a major wastewater stream generated during oil and gas production processes. Due to increase oil and gas exploration and production, especially from unconventional resources like shale oil and gas reservoirs, the volume of this effluent production is increasing around the world and its discarding to the environment is one of the global concerns. There are various physical and chemical methods to treat the produced water. However, a comprehensive and deep understanding of each issue can lead to a better and more efficient solution. In this study, various physical and chemical treatment methods for produced water have been reviewed based on the latest findings and recently published articles on this topic. Moreover, challenges and opportunities of each of these treatment methods have been fully discussed. Also potential applications for reusing the treated PW have been suggested and discussed finally.

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Abstract:
The environmental impact of shale oil and gas production by hydraulic fracturing (fracking) is of increasing concern. The biggest potential source of environmental contamination is flowback and produced water, which is highly contaminated with hydrocarbons, bacteria and particulates, meaning that traditional membranes are readily fouled. We show the chemical functionalisation of alumina ceramic microfiltration membranes (0.22 μm pore size) with cysteic acid creates a superhydrophilic surface, allowing for separation of hydrocarbons from frac and produced waters without fouling. The single pass rejection coefficients was >90% for all samples. The separation of hydrocarbons from water when the former have hydrodynamic diameters smaller than the pore size of the membrane is due to the zwitter ionically charged superhydrophilic pore surface. Membrane fouling is essentially eliminated, while a specific flux is obtained at a lower pressure (<2 bar) than that required achieving the same flux for the untreated membrane (4–8 bar).

Abstract:
Nanoscale zero-valent iron (nZVI) was tested for the removal of Cu(II), Zn(II), Cr(VI), and As(V) in model saline wastewaters from hydraulic fracturing. Increasing ionic strength (I) from 0.35 to 4.10 M (Day-1 to Day-90 wastewaters) increased Cu(II) removal (25.4–80.0%), inhibited Zn(II) removal (58.7–42.9%), slightly increased and then reduced Cr(VI) removal (65.7–44.1%), and almost unaffected As(V) removal (66.7–75.1%) by 8-h reaction with nZVI at 1–2 g L−1. The removal kinetics conformed to pseudo-second-order model, and increasing I decreased the surface area-normalized rate coefficient (ksa) of Cu(II) and Cr(VI), probably because agglomeration of nZVI in saline wastewaters restricted diffusion of metal(loid)s to active surface sites. Increasing I induced severe Fe dissolution from 0.37-0.77% in DIW to 4.87–13.0% in Day-90 wastewater; and Fe dissolution showed a significant positive correlation with Cu(II) removal. With surface stabilization by alginate and polyvinyl alcohol, the performance of entrapped nZVI in Day-90 wastewater was improved for Zn(II) and Cr(VI), and Fe dissolution was restrained (3.20–7.36%). The X-ray spectroscopic analysis and chemical speciation modelling demonstrated that the difference in removal trends from Day-1 to Day-90 wastewaters was attributed to: (i) distinctive removal mechanisms of Cu(II) and Cr(VI) (adsorption, (co-)precipitation, and reduction), compared to Zn(II) (adsorption) and As(V) (bidentate inner-sphere complexation); and (ii) changes in solution speciation (e.g., from Zn2+ to ZnCl3− and ZnCl42−; from CrO42− to CaCrO4 complex). Bare nZVI was susceptible to variations in wastewater chemistry while entrapped nZVI was more stable and environmentally benign, which could be used to remove metals/metalloids before subsequent treatment for reuse/disposal.

Abstract:
Scale-up of microalgal biotechnology to provide large quantities of biofuel, lipids, and coproducts is not fully developed because of the large needs for nutrients, water, land, solar insolation, and CO2/carbon supplies. Wastewaters, including oil and gas produced water (PW), may supply a portion of these needs in regions with insufficient fresh water resources. PW is a challenging water resource for this use because of variable salinity, geochemical complexity, and the presence of biologically toxic components. In this paper we review PW volumes, quality, and use in media for microalgae production in the southwestern US, Australia, and Oman. We also include data from the southwestern US, referencing previously unpublished results from the National Alliance for Biofuels and Bioproducts (NAABB) consortium research project. We include a Supplementary Information section that explores cultivation of multiple microalgae species in PW and examines the carbon utilization process, all work performed in support of the NAABB field program. Strains of algae tested in the reviewed papers include Nannochloropsis, Dunalliella, Scenedesmus, and several mixed or unknown cultures. We conclude that the use of PW in algae cultivation is feasible, if the additional complexity of the water resource is accounted for in developing media formulations and in understanding metals uptake by the algae. We recommend additional work to standardize growth testing in PW, better and more thorough chemical analysis, and geochemical modeling of the PW used in media. Expanded strain testing in PW media will identify improved strains tolerant of PW in algae cultivation.

Abstract:
The current California drought has reduced freshwater availability, creating tensions between water users across the state. Although over 518 million m 3 of water were produced during fossil fuel production in California in 2014, the majority was disposed into Class II injection wells. There have been few attempts to assess the feasibility of using produced water for beneficial purposes, due in part to the difficulties of accessing, synthesizing and analyzing data regarding produced water quality and quantity. This study addresses this gap and provides a techno-economic assessment of upgrading produced water from California’s oil and natural gas activities and moving it to adjacent water-stressed regions. Results indicate that the four population centers facing the greatest water shortage risk are located in the Central Valley within a 161 km (100 mile) radius of 230 million m 3 of total treatable produced water. This volume can supply up to one million people-years worth of potable water. The cost of desalinating and transporting this water source is comparable in magnitude to some agricultural and local public water supplies and is substantially lower than bottled water. Thus, utilizing reverse osmosis to treat produced water might be a feasible solution to help relieve water scarcity in some drought-stricken regions of California.

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The rapidly increasing implementations of oilfield technologies such as horizontal wells and multistage hydraulic fracturing, particularly in unconventional formations, have expanded the need for fresh water in many oilfield locations. In the meantime, it is costly for services companies and operators to properly dispose large volumes of produced water, generated annually at about 21 billion barrels in the United States alone. The high operating costs in obtaining fresh water and dealing with produced water have motivated scientists and engineers, especially in recent years, to use produced water in place of fresh water to formulate well treatment fluids. The objective of this brief review is to provide a summary of the up-to-date technologies of reusing oilfield produced water in preparations of a series of crosslinked fluids implemented mainly in hydraulic fracturing operations. The crosslinked fluids formulated with produced water include borate- and metal-crosslinked guar and derivatized guar fluids, as well as other types of crosslinked fluid systems such as crosslinked synthetic polymer fluids and crosslinked derivatized cellulose fluids. The borate-crosslinked guar fluids have been successfully formulated with produced water and used in oilfield operations with bottomhole temperatures up to about 250 °F. The produced water sources involved showed total dissolved solids (TDS) up to about 115,000 mg/L and hardness up to about 11,000 mg/L. The metal-crosslinked guar fluids prepared with produced water were successfully used in wells at bottomhole temperatures up to about 250 °F, with produced water TDS up to about 300,000 mg/L and hardness up to about 44,000 mg/L. The Zr-crosslinked carboxymethyl hydroxypropyl guar (CMHPG) fluids have been successfully made with produced water and implemented in operations with bottomhole temperatures at about 250+ °F, with produced water TDS up to about 280,000 mg/L and hardness up to about 91,000 mg/L. In most of the cases investigated, the produced water involved was either untreated, or the treatments were minimum such as simple filtration without significantly changing the concentrations of monovalent and divalent ions in the water. Due to the compositional similarity (high salinity and hardness) between produced water and seawater, crosslinked fluids formulated with seawater for offshore and onshore jobs were also included. The crosslinked guar and derivatized guar fluids have been successfully formulated with seawater for operations at bottomhole temperatures up to about 300 °F. Operating costs have been significantly reduced when produced water or seawater is used to formulate fracturing fluids in place of fresh water. With various challenges and limitations still existing, the paper emphasizes the needs for new developments and further expansion of produced water reuse in oilfield operations.

Abstract:
Flowback water generated during shale gas extraction in Pennsylvania is mostly reused for hydraulic fracturing operation. Abandoned mine drainage (AMD), one of the most widespread threats to water quality in Pennsylvania, can potentially serve as a make-up water source to enable flowback water reuse. This study demonstrated co-treatment of flowback water and AMD produced in northeastern Pennsylvania in a pilot-scale system consisting of rapid mix reactor, flocculation tank and sedimentation tank. Sulfate concentration in the finished water can be controlled at a desired level (i.e., below 100 mg/L) by adjusting the ratio of flowback water and AMD in the influent. Fe3+ contained in the AMD can serve as a coagulant to enhance the removal of suspended solids, during which Fe2+ is co-precipitated and the total iron is reduced to a desirable level. Solid waste generated in this process (i.e., barite) will incorporate over 99% of radium present in the flowback water, which offers the possibility to control the fate of naturally occurring radioactive materials (NORM) brought to the surface by unconventional gas extraction. Sludge recirculation in the treatment process can be used to increase the size of barite particles formed by mixing flowback water and AMD to meet specifications for use as a weighting agent in drilling fluid. This alternative management approach for NORM can be used to offset the treatment cost and promote flowback water reuse, reduce environmental impacts of AMD and reduce pressure on fresh water sources.

Abstract:
The toxicity of shale gas fracturing flowback fluid in the eastern Sichuan Basin was investigated and proven to be nontoxic. Based on the water quality characteristics of the fracturing flowback fluid in this area, an experimental study of treatment processes was conducted considering the coagulation–Fenton oxidation processes. Orthogonal and single-factor experiments were carried out for the coagulation and Fenton oxidation processes, respectively. The appropriate values of the various factors affecting the coagulation and Fenton oxidation experiments were determined according to the results. Subsequently, the water quality of the effluent treated by the coagulation–Fenton oxidation processes was evaluated, and the result showed that the water quality requirements for underground injection were met. Finally, the performances of slick water prepared by the effluent were evaluated, and the results showed that the slick water met the demands of fracturing operations and could be reused for further fracturing jobs.

Abstract:
Since the beginning of this millennium, shale gas extraction by horizontal drilling and hydraulic fracturing has boosted U.S. gas production, changing the global energy markets and leading to low natural gas and oil prices. Following the expansion of this industry, other countries such as U.K., Poland or China are exploring and supporting its extraction as a way to secure energy independence in an increasingly unstable geopolitical context and as an effective transition substitute for coal while moving towards a renewable energy market. However, there are important environmental concerns associated to shale gas production including atmospheric pollution and air quality issues, risks of water pollution and nuisance to the population caused by road traffic and noise. Water management is one of the most challenging problems since hydraulic fracturing requires millions of liters of water and produces high volumes of liquid effluents at variable compositions and rates. The present review focuses on the characteristics of this wastewater and the options existing to minimize its environmental impacts. At the moment, deep well injection and re-use are the most commonly employed strategies for this wastewater in the U.S. but the stricter regulations in other regions will require further treatment. Partial treatment and reuse is the preferred option where feasible. Otherwise, techniques such as mechanical vapor compression, thermal distillation or forward osmosis may be needed in order to meet the requirements for discharge.

Abstract:
A review of the literature published in 2015 on topics relating to public and environmental health risks associated with wastewater treatment, reuse, and disposal is presented. This review is divided into the following sections: wastewater management, microbial hazards, chemical hazards, wastewater treatment, wastewater reuse, agricultural reuse in different regions, greywater reuse, wastewater disposal, hospital wastewater, industrial wastewater, and sludge and biosolids.

Abstract:
Rapid development of hydraulic fracturing for natural gas production from shale reservoirs presents a significant challenge related to the management of the high-salinity wastewaters that return to the surface. In addition to high total dissolved solids (TDS), shale gas-produced brines typically contain elevated concentrations of radium (Ra), which must be treated properly to prevent contamination of surface waters and allow for safe disposal or reuse of produced water. Treatment strategies that isolate radium in the lowest volume waste streams would be desirable to reduce disposal cost and generate useful treatment by-products. The present study evaluates the potential of a commercial strong acid cation exchange resin for removing Ra2+ from high-TDS brines using fixed-bed column reactors. Column reactors were operated with varying brine chemistries and salinities in an effort to find optimal conditions for Ra2+ removal through ion exchange. To overcome competing divalent cations present in the brine for exchange sites, the chelating agent, EDTA, was used to form stable complexes predominantly with the higher concentration Ca2+, Mg2+, and Sr2+ divalent cations, while isolating the much lower concentration Ra2+ species. Results showed that Ra2+ removal by the resin strongly depended on the TDS concentration and could be improved with careful selection of EDTA concentration. This strategy of metal chelation coupled with ion exchange resins may be effective in enhancing Ra2+ removal and reducing the generation and disposal cost if volume reduction of low-level radioactive solid waste can be achieved.

Abstract:
The objective of this study was to understand the adsorption ability of a surfactant and a non-surfactant chemical additive used in hydraulic fracturing onto shale and GAC. Experiments were performed at varying temperatures and sodium chloride concentrations to establish these impacts on the adsorption of the furfural (a non-surfactant) and 2-Butoxyethanol (2-BE) (a surfactant). Experiments were carried out in continuously mixed batch experiments with Langmuir and Freundlich isotherm modeling. The results of the experiments showed that adsorption of these compounds onto shale does not occur, which may allow these compounds to return to the surface in flowback and produced waters. The adsorption potential for these chemicals onto GAC follows the assumptions of the Langmuir model more strongly than those of the Freundlich model. The results show uptake of furfural and 2-BE occurs within 23 h in the presence of DI water, 0.1 mol L(-1) sodium chloride, and in lab synthesized hydraulic fracturing brine. Based on the data, 83% of the furfural and 62% of the 2-BE was adsorbed using GAC.

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Abstract:
One of the environmental risks associated with use of hydraulic fracturing stimulation technologies for oil and natural gas recovery is the potential release of used fluids into surface waters, soils, and groundwater that could contaminate drinking water resources. To better characterize biodegradability of organic additives, we developed a synthetic fracturing fluid (SFF) based on industry-disclosed formulas, compared its organic carbon composition to fluids used in Pennsylvania's Marcellus shale, and amended agricultural soil–groundwater microcosms with three different SFF concentrations to determine organic carbon degradation rates, changes in system biogeochemistry, and microbial community dynamics under aerobic and anaerobic conditions. Microorganisms indigenous to soils and groundwater were able to degrade between 70% and 92% of the amended dissolved organic carbon within 39 days, suggesting significant mineralization, transformation, or biomass assimilation of organic additives across anaerobic and aerobic redox conditions. Sequencing analysis of the 16S rRNA gene revealed a greater abundance of Pseudomonas in aerobic treatments and a higher relative portion of Desulfovibrio in anaerobic treatments amended with SFF, indicating that these taxa may be involved in SFF biodegradation processes under specific redox conditions. Results provide insight into biodegradability of hydraulic fracturing fluid organic additives in shallow agricultural soils and groundwater and biogeochemical processes that may attenuate their migration if accidentally released or spilled at the surface during hydraulic fracturing activities.

Abstract:
Summary Recycling oilfield wastewater for hydraulic fracturing requires a good understanding of the water chemical characteristics and how these interact with the fracturing fluid. The viscosity and rheological properties of fracturing fluids affect

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Underground injection (UI) is an effective and efficient means of disposing of wastewater from shale gas production. However, the influence of UI on groundwater systems should be examined carefully to protect drinking groundwater sources. A regional hydrogeological model based on TOUGH2-MP/EOS7R of part of the Sichuan Basin is established to simulate pressure changes and solute transport in response to wastewater injection into deep aquifers. Wastewater is assumed to be injected through a well at a rate of 5.45 kg s−1 for 5 years and a post-injection period of 45 years. The simulation results indicate that UI will cause significant pressure buildup during the injection period, after which pressure will dissipate during the post-injection period. The mass fraction of solute increased over the entire simulation period. The draft regulation under the Safe Drinking Water Act and the level III groundwater quality standards regulated by the Chinese government is referenced as the criteria for evaluating the influence of UI on groundwater systems. It is found that maximum pressure levels caused by UI may exceed safe levels. Uncertainties with respect to permeability are analyzed from previous studies and injection test results. Lower levels of permeability incur higher degrees of pressure buildup when UI is implemented. Different injection schemes are discussed, and we verify that pressure buildup from time-variant injection schemes is less than that from constant injection schemes for the same total injection volume. Injection schemes should be carefully evaluated before implementing UI in a shale gas reservoir.

Abstract:
Management of Marcellus Shale flowback water is a rising concern in Pennsylvania. Due to limited capacity for wastewater disposal by deep-well injection, flowback water reuse is the dominant management option in PA. Microfiltration is a promising technology to be used in a mobile treatment system for solids removal from Marcellus Shale flowback water prior to reuse. It was found previously that early Marcellus Shale flowback water could cause severe membrane fouling due to the presence of stable submicron colloids. Bench-scale cross-flow filtration system was used in this study to evaluate the feasibility of microfiltration for treatment of Marcellus Shale flowback water that does not contain these submicron colloids. The performance of alumina (Al2O3) and silicon carbide (SiC) ceramic membranes that have distinct surface charge properties was evaluated in this system using a constant transmembrane pressure. The difference in the isoelectric point of these membranes suggested possible differences in fouling behavior, but extremely high salinity of the flowback water screened the electrostatic interactions and minimized these differences. For the two flowback waters tested in this study, the one with lower TDS caused more severe fouling of both SiC and Al2O3 membranes during the first 15 min of filtration. The flux decline analysis revealed that intermediate pore blocking was the dominant fouling mechanism in the early filtration stage. Such behavior was due to the fact that the particulate matter in this flowback water was in the aggregate form and the flocs were prone to breakup at elevated shear stress caused by high pumping rate. Despite having much higher TSS, the other flowback water did not cause excessive membrane fouling due to stability and strength of its original particles.

Abstract:
Pennsylvania's rapid unconventional oil and gas (UOG) development-from a single well in 2004 to more than 6700 wells in 2013-has dramatically increased UOG waste transport by heavy trucks. This study quantified the amount of UOG waste and the distance it traveled between wells and disposal facilities on each type of road in each county between July 2010 and December 2013. In addition, the study estimated the associated financial costs to each county's road infrastructure over that period. We found that UOG wells produced a median wastewater volume of 1294 m(3) and a median of 89,267 kg of solid waste. The median number of waste-transport truck trips per well was 122. UOG wells existed in 38 Pennsylvania counties, but we estimated trucks transporting well waste traveled through 132 counties, including counties in West Virginia, Ohio, and New York. Median travel distance varied by disposal type, from 106 km to centralized treatment facilities up to 237 km to injection wells. Local roads experienced the greatest amount of truck traffic and associated costs ($1.1-6.5 M) and interstates, the least ($0.3-1.6 M). Counties with oil and gas development experienced the most truck traffic and incurred the highest associated roadway costs. However, many counties outside the active development area also incurred roadway repair costs, highlighting the extension of UOG development's spatial footprint beyond the active development area. An online data visualization tool is available here: www.nicholasinstitute.duke.edu/transportation-of-hydraulic-fracturing-waste.

Abstract:
Unconventional resource extraction from shale plays involves complex operations for water and wastewater management. These water management operations are expensive for companies and emit significant quantities of criteria air pollutants and greenhouse gases that impact human health and the environment (HHE). We present a multiobjective mixed integer linear programming (MILP) framework for assessing the trade-offs between financial cost and HHE costs for shale gas water acquisition, transport, storage, and treatment under realistic scheduling, operational, and regulatory constraints. We formulate objective functions to identify water management strategies that minimize financial cost, minimize HHE cost, and minimize combined financial and HHE costs. The model was applied to a 14 wellpad case study that is representative of shale gas extraction in the Marcellus Play. We observe significant variation in the financial and HHE costs under different objective functions and regulatory scenarios.

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Produced and flowback waters are the largest byproducts associated with unconventional oil and gas exploration and production. Sustainable and low cost technologies are needed to treat and reuse this wastewater to avoid the environmental problems associated with current management practices (i.e., deep well injection). This study presents a new process to integrate AC-powered electrocoagulation (EC) with granular biochar to dramatically reduce energy use and electrode passivation while achieving high treatment efficiency. Results show achieving a 99% turbidity and TSS removal for the AC-EC-biochar system only used 0.079 kWh/m3 or 0.15 kWh/kg TSS, which is 70% lower than traditional DC-EC systems and orders of magnitude lower than previous studies. The amount of biochar added positively correlates with energy saving, and further studies are needed to improve organic carbon and salt removal through system integration.

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This article presents a mathematical programing formulation for the optimal management of flowback water in shale gas wells. The formulation accounts for the time-based generation of the flowback water, the options for treatment, storage, reuse, and disposal. The economic and environmental objectives are considered. The economic objective function is aimed at determining the minimum cost for the fresh water, treatment, storage, disposals, and transportation. The environmental objectives account for the fresh water usage and wastewater discharge. To carry out the water integration, a reuse network including treatment is proposed. Additionally, the model considers seasonal fluctuations in the fresh water availability. A given scheduling for the completion phases of the wells is required to implement the methodology. Finally, an example problem is presented to show the applicability of the proposed methodology. © 2016 American Institute of Chemical Engineers AIChE J, 62: 1634–1645, 2016

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Wastewater produced by hydraulic fracturing for oil and gas production is characterized by high salinity and high chemical oxygen demand (COD). We applied a combination of flocculation and wet air oxidation technology to optimize the reduction of COD in the treatment of hydraulic fracturing wastewater. The experiments used different values of flocculant, coagulant, and oxidizing agent added to the wastewater, as well as different reaction times and treatment temperatures. The use of flocculants for the pretreatment of fracturing wastewater was shown to improve treatment efficiency. The addition of 500 mg/L of polyaluminum chloride (PAC) and 20 mg/L of anionic polyacrylamide (APAM) during pretreatment resulted in a COD removal ratio of 8.2% and reduced the suspended solid concentration of fracturing wastewater to 150 mg/L. For a solution of pretreated fracturing wastewater with 12 mL of added H2O2, the COD was reduced to 104 mg/L when reacted at 300 °C for 75 min, and reduced to 127 mg/L when reacted at the same temperature for 45 min while using a 1 L autoclave. An optimal combination of these parameters produced treated wastewater that met the GB 8978-1996 'Integrated Wastewater Discharge Standard' level I emission standard.

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The Marcellus Shale formation contains large natural gas reserves, which are increasingly being extracted using horizontal drilling techniques. Concerns about environmental effects have prompted studies regarding Marcellus operations, including the safety of pits and impoundments containing frac fluids and freshwater. A subset of these structures in West Virginia was evaluated using a risk-based field data collection tool, which revealed recurring problems. A probability-based method was developed to determine the likelihood of these problems occurring in larger sample sizes. Applying this method to portfolios of pits and impoundments would benefit the industry by identifying areas of improvement for construction and inspection.

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This paper presents a mathematical programing formulation for synthesizing water networks associated with shale gas hydraulic fracturing operations while accounting for the system uncertainty. The proposed formulation yields strategic planning that minimizes the cost considering water requirements as well as equipment capacities for treatment technologies, storage units, and disposals. The key uncertainties pertain to the water usage for fracturing and the time-based return of flowback water. The objective function is aimed at the minimization of the total annual cost, which accounts for the operating and capital costs associated with the water network. The developed model addresses the scheduling problem associated with shale gas production, which provides as output the completion phases for all the projected wells. This information is used in estimating the periods with water requirements and where flowback water can be collected. The proposed methodology includes an analysis of the optimal equipment size. An illustrative example is presented to show the capabilities of the proposed methodology.

Abstract:
In 2010, a dramatic increase in the levels of total trihalomethane (THM) and the relative proportion of brominated species was observed in finished water at several Pennsylvania water utilities (PDW) using the Allegheny River as their raw water supply. An increase in bromide (Br−) concentrations in the Allegheny River was implicated to be the cause of the elevated water disinfection byproducts. This study focused on quantifying the contribution of Br− from a commercial wastewater treatment facility (CWTF) that solely treats wastes from oil and gas producers and discharges into the upper reaches of the Allegheny River, and impacts on two downstream PDWs. In 2012, automated daily integrated samples were collected on the Allegheny River at six sites during three seasonal two-week sampling campaigns to characterize Br− concentrations and river dispersion characteristics during periods of high and low river discharges. The CWTF discharges resulted in significant increases in Br− compared to upstream baseline values in PDW raw drinking water intakes during periods of low river discharge. During high river discharge, the assimilative dilution capacity of the river resulted in lower absolute halide concentrations, but significant elevations Br− concentrations were still observed at the nearest downstream PDW intake over baseline river levels. On days with active CWTF effluent discharge the magnitude of bromide impact increased by 39 ppb (53%) and 7 ppb (22%) for low and high river discharge campaigns, respectively. Despite a declining trend in Allegheny River Br− (2009–2014), significant impacts from CWTF and coal-fired power plant discharges to Br− concentrations during the low river discharge regime at downstream PDW intakes was observed, resulting in small modeled increases in total THM (3%), and estimated positive shifts (41–47%) to more toxic brominated THM analogs. The lack of available coincident measurements of THM, precursors, and physical parameters limited the interpretation of historical trends.

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This work presents an optimization framework for evaluating different wastewater treatment/disposal options for water management during hydraulic fracturing (HF) operations. This framework takes into account both cost-effectiveness and system uncertainty. HF has enabled rapid development of shale gas resources. However, wastewater management has been one of the most contentious and widely publicized issues in shale gas production. The flowback and produced water (known as FP water) generated by HF may pose a serious risk to the surrounding environment and public health because this wastewater usually contains many toxic chemicals and high levels of total dissolved solids (TDS). Various treatment/disposal options are available for FP water management, such as underground injection, hazardous wastewater treatment plants, and/or reuse. In order to cost-effectively plan FP water management practices, including allocating FP water to different options and planning treatment facility capacity expansion, an optimization model named UO-FPW is developed in this study. The UO-FPW model can handle the uncertain information expressed in the form of fuzzy membership functions and probability density functions in the modeling parameters. The UO-FPW model is applied to a representative hypothetical case study to demonstrate its applicability in practice. The modeling results reflect the tradeoffs between economic objective (i.e., minimizing total-system cost) and system reliability (i.e., risk of violating fuzzy and/or random constraints, and meeting FP water treatment/disposal requirements). Using the developed optimization model, decision makers can make and adjust appropriate FP water management strategies through refining the values of feasibility degrees for fuzzy constraints and the probability levels for random constraints if the solutions are not satisfactory. The optimization model can be easily integrated into decision support systems for shale oil/gas lifecycle management. (C) 2015 Elsevier Ltd. All rights reserved.

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The objective of this paper is to review different risk assessment techniques applicable to onshore unconventional oil and gas production to determine the risks to water quantity and quality associated with hydraulic fracturing and produced water management. Water resources could be at risk without proper management of water, chemicals, and produced water. Previous risk assessments in the oil and gas industry were performed from an engineering perspective leaving aside important social factors. Different risk assessment methods and techniques are reviewed and summarized to select the most appropriate one to perform a holistic and integrated analysis of risks at every stage of the water life cycle. Constraints to performing risk assessment are identified including gaps in databases, which require more advanced techniques such as modeling. Discussions on each risk associated with water and produced water management, mitigation strategies, and future research direction are presented. Further research on risks in onshore unconventional oil and gas will benefit not only the U.S. but also other countries with shale oil and gas resources.

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Hydraulic fracturing has advanced the development of shale gas extraction, while inadvertent spills of flowback water may pose a risk to the surrounding environment due to its high salt content, metals/metalloids (As, Se, Fe and Sr), and organic additives. This study investigated the potential impact of flowback water on four representative soils from shale gas regions in Northeast China using synthetic flowback solutions. The compositions of the solutions were representative of flowback water arising at different stages after fracturing well establishment. The effects of solution composition of flowback water on soil ecosystem were assessed in terms of metal mobility and bioaccessibility, as well as biological endpoints using Microtox bioassay (Vibrio fischeri) and enzyme activity tests. After one-month artificial aging of the soils with various flowback solutions, the mobility and bioaccessibility of As(V) and Se(VI) decreased as the ionic strength of the flowback solutions increased. The results inferred a stronger binding affinity of As(V) and Se(VI) with the soils. Nevertheless, the soil toxicity to Vibrio fischeri only presented a moderate increase after aging, while dehydrogenase and phosphomonoesterase activities were significantly suppressed with increasing ionic strength of flowback solutions. On the contrary, polyacrylamide in the flowback solutions led to higher dehydrogenase activity. These results indicated that soil enzyme activities were sensitive to the composition of flowback solutions. A preliminary human health risk assessment related to As(V) suggested a low level of cancer risk through exposure via ingestion, while holistic assessment of environmental implications is required.

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Shale gas exploitation by hydraulic fracturing involves a number of environmental hazards, among which the neutralization and management of fracturing flowback waters is of particular importance. Chemical compounds present in the flowback water mainly constitute a threat to surface waters. The aim of our research was to determine the effects of these compounds on the state of activated sludge in a wastewater treatment plant employing biological treatment processes. Based on the obtained results, it was concluded that prior to the transfer of flowback water to a biological wastewater treatment system, it should be diluted with fresh water to lower the chloride ion concentration to the level of 1,000 mg Cl-/dm3. Although such a procedure would ensure the proper performance of a biological wastewater treatment system, it would not limit the migration of phthalates and thihalomethanes to surface waters.

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Hydraulic fracturing is the process of injecting solutions at high pressure to break apart rock formations and increase efficiency of natural gas extraction. The solutions are recovered and have been land-applied as a disposal technique. The objective of this greenhouse study was to evaluate the effects of inorganic fertilizer, broiler litter, or Milorganite®, and soil depth interval on the growth of Bermuda grass [Cynodon dactylon (L.) Pers] in soil from a site that had been contaminated with fracturing fluid and was devoid of vegetation. In soil from 0–15 cm depth, initial electrical conductivity (ECe), Na, and Cl levels were 14.5 dS/m, 2994 mg/kg, and 5603 mg/kg, respectively. For the 0–30 cm depth, initial ECe, Na, and Cl levels were 14.1 dS/m, 2550 mg/kg, and 5020 mg/kg, respectively. Bermuda grass was sprigged and harvested after nine weeks. Addition of inorganic fertilizer, broiler litter, or Milorganite® resulted in 290, 241, and 172%, respectively, greater shoot biomass compared to unamended soil. Plants grown in the 0–30 cm depth soil had greater root biomass (95%), length (67%), volume (61%), and surface area (65%) compared to those grown in soil from the 0–15 cm depth. Fertilization and cultivation may be useful in revegetating sites contaminated with fracturing fluid.

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Managing the wastewater discharged from oil and shale gas fields is a big challenge, because this kind of wastewater is normally polluted by high contents of both oils and salts. Conventional pressure-driven membranes experience little success for treating this wastewater because of either severe membrane fouling or incapability of desalination. In this study, we designed a new nanocomposite forward osmosis (FO) membrane for accomplishing simultaneous oil/water separation and desalination. This nanocomposite FO membrane is composed of an oil-repelling and salt-rejecting hydrogel selective layer on top of a graphene oxide (GO) nanosheets infused polymeric support layer. The hydrogel selective layer demonstrates strong underwater oleophobicity that leads to superior anti-fouling capability under various oil/water emulsions, and the infused GO in support layer can significantly mitigate internal concentration polarization (ICP) through reducing FO membrane structural parameter by as much as 20%. Compared with commercial FO membrane, this new FO membrane demonstrates more than three times higher water flux, higher removals for oil and salts (>99.9% for oil and >99.7% for multivalent ions) and significantly lower fouling tendency when investigated with simulated shale gas wastewater. These combined merits will endorse this new FO membrane with wide applications in treating highly saline and oily wastewaters.

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Volumes of natural gas extraction-derived wastewaters have increased sharply over the past decade, but the ultimate fate of those waste streams is poorly characterized. Here, we sought to (a) quantify natural gas residual fluid sources and endpoints to bound the scope of potential waste stream impacts and (b) describe the organic pollutants discharged to surface waters following treatment, a route of likely ecological exposure. Our findings indicate that centralized waste treatment facilities (CWTF) received 9.5% (8.5 ? 108 L) of natural gas residual fluids in 2013, with some facilities discharging all effluent to surface waters. In dry months, discharged water volumes were on the order of the receiving body flows for some plants, indicating that surface waters can become waste-dominated in summer. As disclosed organic compounds used in high volume hydraulic fracturing (HVHF) vary greatly in physicochemical properties, we deployed a suite of analytical techniques to characterize CWTF effluents, covering 90.5% of disclosed compounds. Results revealed that, of nearly 1000 disclosed organic compounds used in HVHF, only petroleum distillates and alcohol polyethoxylates were present. Few analytes targeted by regulatory agencies (e.g., benzene or toluene) were observed, highlighting the need for expanded and improved monitoring efforts at CWTFs.

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Environmental context There is growing worldwide interest in the production of oil and gas from deep, shale formations following advances in the technical expertise to exploit these resources such as hydraulic fracturing (fracking). The potential widespread application of hydraulic fracturing has raised concerns over deleterious environmental impacts on fragile water resources. We discuss the environmental management challenges faced by the oil and gas industry, and the opportunities for innovation in the industry. Abstract The need for cheap and readily available energy and chemical feedstock, and the desire for energy independence have spurred worldwide interest in the development of unconventional oil and gas resources; in particular, the production of oil and gas from shale formations. Although these resources have been known for a long time, the technical expertise and market forces that enable economical development has coincided over the last 15 years. The amalgamation of horizontal drilling and hydraulic fracturing have enabled favourable economics for development of fossil energy from these unconventional reservoirs, but their potential widespread application has raised concerns over deleterious environmental impacts on fragile water resources. The environmental management challenges faced by the oil and gas industry arise from local water availability and infrastructure for treating and disposing of the high-strength wastewater that is produced. Although there are significant challenges, these create opportunities for innovation in the industry.

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A suite of analytical tools was applied to thoroughly analyze the chemical composition of an oil/gas well flowback water from the Denver–Julesburg (DJ) basin in Colorado, and the water quality data was translated to propose effective treatment solutions tailored to specific reuse goals. Analysis included bulk quality parameters, trace organic and inorganic constituents, and organic matter characterization. The flowback sample contained salts (TDS = 22,500 mg/L), metals (e.g., iron at 81.4 mg/L) and high concentration of dissolved organic matter (DOC = 590 mgC/L). The organic matter comprised fracturing fluid additives such as surfactants (e.g., linear alkyl ethoxylates) and high levels of acetic acid (an additives' degradation product), indicating the anthropogenic impact on this wastewater. Based on the water quality results and preliminary treatability tests, the removal of suspended solids and iron by aeration/precipitation (and/or filtration) followed by disinfection was identified as appropriate for flowback recycling in future fracturing operations. In addition to these treatments, a biological treatment (to remove dissolved organic matter) followed by reverse osmosis desalination was determined to be necessary to attain water quality standards appropriate for other water reuse options (e.g., crop irrigation). The study provides a framework for evaluating site-specific hydraulic fracturing wastewaters, proposing a suite of analytical methods for characterization, and a process for guiding the choice of a tailored treatment approach.

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The reuse of produced water generated by natural gas extraction from Marcellus Shale for hydraulic fracturing is the dominant management option in Pennsylvania (PA), USA. The advantages and disadvantages of this management approach are reviewed and discussed together with long-term concerns and technology development needs. Abandoned mine drainage is a promising alternative make-up water, but high sulfate concentrations will lead to barite precipitation once it is mixed with the produced water. Bench-scale studies were conducted to optimize barite separation from this mixture that meets the finished water quality criteria for sulfate. Conventional separation processes are very effective in removing these solids but radium (Ra) co-precipitation may be a concern for their disposal in municipal landfills. If the produced water volume exceeds the reuse capacity for hydraulic fracturing, lime–soda ash softening can be used to remove divalent cations, including radium, to enable the production of pure salts using subsequent thermal processes.

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Economic production from tight sand gas reservoirs usually involves multistage hydraulic fracturing. High costs of water acquisition and waste water disposal, and the lack of available water resources near operation sites, make the reuse of produced water an unavoidable option. However, recycling produced water in hydraulic fracturing jobs result in low quality fracturing fluids, which usually have high levels of hardness and salinity. This is especially true for flowback fluids, which contain high polymer loading. The viscosity and rheological properties of fracturing fluids significantly affect leak-off rate, proppant placement, length and width of fractures, fracture conductivity, and consequently, the success of the treatment. The objective of this study is to determine the acceptable dissolved solid contents for flowback fluids to prepare fracturing fluids. Analyses of 36 flowback fluid samples from the West Texas region were collected, and experimental studies were conducted on the analysis of the dissolved solids of produced water, which affect the application of flowback fluids and the capability of prepared fluids in proppant transport and handling. A high-pH borate crosslinked guar-based polymer was selected to determine the ranges of acceptable salt contents. Dynamic viscosity and rheological properties tests, static proppant settling, and small-amplitude oscillation rheology were the methods used to evaluate prepared samples at low, medium, and high temperatures up to 305 °F (152 °C). Some divalent cations such as calcium and magnesium have negative effects on the prepared polymers. Magnesium is the controlling ion, and approximately 30% of flowback fluids must be treated to meet the maximum acceptable concentration criterion. While monovalent cations such as sodium and potassium were tolerable at higher concentrations and the potassium contents in almost all flowback fluids met the determined acceptable value, more than 40% of samples required treatment for high sodium ion concentrations. Although the presence of other ions such as iron shows no significant variation in fracturing fluid properties, they can affect treatment in special cases. Adjusting the concentrations of the polymer, buffer, and crosslinker can minimize the adverse effects of temperature and salts. The fluids prepared with the determined ranges of dissolved solids showed reasonable thermal stability and proppant transport characteristics. This paper introduces the practical operating range for produced water composition and defines the ions that can adversely impact borate-crosslinked fracturing fluid characteristics at different temperatures.

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The rapid development of unconventional oil and gas production has generated large amounts of wastewater for disposal, raising significant environmental and public health concerns. Treatment and beneficial use of produced water presents many challenges due to its high concentrations of petroleum hydrocarbons and salinity. The objectives of this study were to investigate the feasibility of treating actual shale gas produced water using a bioelectrochemical system integrated with capacitive deionization-a microbial capacitive desalination cell (MCDC). Microbial degradation of organic compounds in the anode generated an electric potential that drove the desalination of produced water. Sorption and biodegradation resulted in a combined organic removal rate of 6.4mg dissolved organic carbon per hour in the reactor, and the MCDC removed 36mg salt per gram of carbon electrode per hour from produced water. This study is a proof-of-concept that the MCDC can be used to combine organic degradation with desalination of contaminated water without external energy input.

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Waters co-produced with hydrocarbons in the Appalachian Basin are of notably poor quality (concentrations of total dissolved solids (TDS) and total radium up to and exceeding 300,000 mg/L and 10,000 pCi/L, respectively). Since 2008, a rapid increase in Marcellus Shale gas production has led to a commensurate rise in associated wastewater while generation of produced water from conventional oil and gas activities has continued. In this study, we assess whether disposal practices from treatment of produced waters from both shale gas and conventional operations in Pennsylvania could result in the accumulation of associated alkali earth elements. The results from our 5 study sites indicate that there was no increase in concentrations of total Ra (Ra-226) and extractable Ba, Ca, Na, or Sr in fluvial sediments downstream of the discharge outfalls (p > 0.05) of publicly owned treatment works (POTWs) and centralized waste treatment facilities (CWTs). However, the use of road spreading of brines from conventional oil and gas wells for deicing resulted in accumulation of Ra-226 (1.2 ×), and extractable Sr (3.0 ×), Ca (5.3 ×), and Na (6.2 ×) in soil and sediment proximal to roads (p < 0.05). Although this study is an important initial assessment of the impacts of these disposal practices, more work is needed to consider the environmental consequences of produced waters management.

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Prerequisite to detailed risk analyses of flowback and produced water management from unconventional resource extraction is the thorough characterization of wastewater management strategies, treatment technologies, prices, and future developments. This expert elicitation compares professional responses on current practices and future trends in wastewater management from Pennsylvania's Marcellus formation across the oil and gas sector, the wastewater treatment sector, and the regulatory sector. Although expert judgments were highly influenced by the respondent's role in unconventional resource development, the results of this expert elicitation suggest that water reuse is not inhibited by high concentrations of total dissolved solids, that waste transport accounts for the majority of the cost associated with off-site wastewater treatment and disposal, and that prices for commercial wastewater treatment are likely to drop over the next five years. Taken together, these results indicate that long-term water reuse is a viable strategy for oil and gas wastewater management among companies with continuous or near continuous drilling operations and that future risk analyses of oil and gas wastewater management should concentrate on reuse activity. The results also suggest that expanding economical water reuse practices to companies that drill fewer sequential or spatially clustered wells may require regulatory or policy intervention. (C) 2014 American Society of Civil Engineers.

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Wastewaters generated during hydraulic fracturing of the Marcellus Shale typically contain high concentrations of salts, naturally occurring radioactive material (NORM), and metals, such as barium, that pose environmental and public health risks upon inadequate treatment and disposal. In addition, fresh water scarcity in dry regions or during periods of drought could limit shale gas development. This paper explores the possibility of using alternative water sources and their impact on NORM levels through blending acid mine drainage (AMD) effluent with recycled hydraulic fracturing flowback fluids (HFFFs). We conducted a series of laboratory experiments in which the chemistry and NORM of different mix proportions of AMD and HFFF were examined after reacting for 48 h. The experimental data combined with geochemical modeling and X-ray diffraction analysis suggest that several ions, including sulfate, iron, barium, strontium, and a large portion of radium (60-100%), precipitated into newly formed solids composed mainly of Sr barite within the first ∼10 h of mixing. The results imply that blending AMD and HFFF could be an effective management practice for both remediation of the high NORM in the Marcellus HFFF wastewater and beneficial utilization of AMD that is currently contaminating waterways in northeastern U.S.A.

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The development of the Marcellus Shale gas play in Pennsylvania and the northeastern United States has resulted in significant amounts of water and wastes transported by truck over roadways. This study used geographic information systems (GIS) to quantify truck travel distances via both the preferred routes (minimum distance while also favoring higher-order roads) as well as, where available, the likely actual distances for freshwater and waste transport between pertinent locations (e.g., gas wells, treatment facilities, freshwater sources). Results show that truck travel distances in the Susquehanna River Basin are greater than those used in prior life-cycle assessments of tight shale gas. When compared to likely actual transport distances, if policies were instituted to constrain truck travel to the closest destination and higher-order roads, transport mileage reductions of 40–80% could be realized. Using reasonable assumptions of current practices, greenhouse gas (GHG) emissions associated with water and waste hauling were calculated to be 70–157 MT CO2eq${\mathrm{CO}}_2\mathrm{eq}$ per gas well. Furthermore, empty so-called backhaul trips, such as to freshwater withdrawal sites or returning from deep well injection sites, were found to increase emissions by an additional 30%, underscoring the importance of including return trips in the analysis. The results should inform future life-cycle assessments of tight shale gases in managed watersheds and help local and regional governments plan for impacts of transportation on local infrastructure.

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