Repository for Oil and Gas Energy Research (ROGER)

Abstract:
When studying technical methods and measures that could be applicable for flowback treatment, recycling and/or disposal, it is important to characterize the volumes and composition of hydraulic fracturing flowback. In this work, water volumes and water quality data are considered for investigating flowback at three selected drilling sites in Germany. The analysis highlighted an increase of chloride concentrations up to saturation limit over the time. High salinity concentrations were used as indicator for estimating the percentage of hydraulic fracturing fluid and formation water in flowback. For the studied shale gas well a proportion of formation water, 69 %, and hydraulic fracturing fluid, 31 %, in flowback were derived. Thus, 92 % of the hydraulic fracturing fluid remained in the formation. The physical/chemical properties of flowback were categorized in groups to enable the allocation of applicable treatment methods. The analysis revealed that no single technology can meet suitable effluent characteristics, thus two or more treatment systems might be used in series operation. In particular, for flowback containing high salinity concentrations the only treatment options are evaporation or crystallization. Hence, methodological distinctions need to be made between concentration, elimination, disposal and recycling, whereby for the existing concentrate treatment or disposal measures need to be completed and scaled up into the process.

Abstract:
In the rapidly developing shale gas industry, managing produced water is a major challenge for maintaining the profitability of shale gas extraction while protecting public health and the environment. We review the current state of practice for produced water management across the United States and discuss the interrelated regulatory, infrastructure, and economic drivers for produced water reuse. Within this framework, we examine the Marcellus shale play, a region in the eastern United States where produced water is currently reused without desalination. In the Marcellus region, and in other shale plays worldwide with similar constraints, contraction of current reuse opportunities within the shale gas industry and growing restrictions on produced water disposal will provide strong incentives for produced water desalination for reuse outside the industry. The most challenging scenarios for the selection of desalination for reuse over other management strategies will be those involving high-salinity produced water, which must be desalinated with thermal separation processes. We explore desalination technologies for treatment of high-salinity shale gas produced water, and we critically review mechanical vapor compression (MVC), membrane distillation (MD), and forward osmosis (FO) as the technologies best suited for desalination of high-salinity produced water for reuse outside the shale gas industry. The advantages and challenges of applying MVC, MD, and FO technologies to produced water desalination are discussed, and directions for future research and development are identified. We find that desalination for reuse of produced water is technically feasible and can be economically relevant. However, because produced water management is primarily an economic decision, expanding desalination for reuse is dependent on process and material improvements to reduce capital and operating costs.

Abstract:
Extraction of natural gas from tight shale formations has been made possible by recent technological advances, including hydraulic fracturing with horizontal drilling. Global shale gas development is seen as a potential energy and geopolitical “game-changer.” However, widespread concern exists with respect to possible environmental consequences of this development, particularly impacts on water resources. In the United States, where the most shale gas extraction has occurred, the Marcellus Shale is now the largest natural gas producing play. To date, over 6,000,000 m3 of wastewater has been generated in the process of extracting natural gas from this shale in the state of Pennsylvania (PA) alone. Here we examine wastewater management practices and trends for this shale play through analysis of industry-reported, publicly available data collected from the Pennsylvania Department of Environmental Protection Oil and Gas Reporting Website. We also analyze the tracking and transport of shale gas liquid waste streams originating in PA using a combination of web-based and GIS approaches. From 2008 to 2011 wastewater reuse increased, POTW use decreased, and data tracking became more complete, while the average distance traveled by wastewater decreased by over 30%. Likely factors influencing these trends include state regulations and policies, along with low natural gas prices. Regional differences in wastewater management are influenced by industrial treatment capacity, as well as proximity to injection disposal capacity. Using lessons from the Marcellus Shale, we suggest that nations, states, and regulatory agencies facing new unconventional shale development recognize that pace and scale of well drilling leads to commensurate wastewater management challenges. We also suggest they implement wastewater reporting and tracking systems, articulate a policy for adapting management to evolving data and development patterns, assess local and regional wastewater treatment infrastructure in terms of capacity and capability, promote well-regulated on-site treatment technologies, and review and update wastewater management regulations and policies.

Abstract:
To produce large volumes of newly discovered unconventional gas, hydraulic fracturing of wells is commonly practiced in basins where shale gas and coal bed methane are extracted. Hydraulic fracturing of wells during oil and gas (O&G) exploration consumes large volumes of fresh water and generates larger volumes of contaminated wastewater. In this study, a novel application of forward osmosis (FO) was tested for treatment and reclamation of water from drilling waste to facilitate beneficial water reuse. By using FO, two major benefits were achieved: both the volume of the waste stream and the need for a fresh water source were greatly reduced. Results indicate that FO can achieve high rejection of organic and inorganic contaminants, membrane fouling was reversible, and that the process was able to effectively recover more than 80% of the water from the drilling waste. Osmotic backwashing was demonstrated to be an effective membrane cleaning technique; successfully removing fouling and restoring water flux.

Abstract:
Hydraulic fracturing has made vast quantities of natural gas from shale available, reshaping the energy landscape of the United States. Extracting shale gas, however, generates large, unavoidable volumes of wastewater, which to date lacks accurate quantification. For the Marcellus shale, by far the largest shale gas resource in the United States, we quantify gas and wastewater production using data from 2189 wells located throughout Pennsylvania. Contrary to current perceptions, Marcellus wells produce significantly less wastewater per unit gas recovered (approximately 35%) compared to conventional natural gas wells. Further, well operators classified only 32.3% of wastewater from Marcellus wells as flowback from hydraulic fracturing; most wastewater was classified as brine, generated over multiple years. Despite producing less wastewater per unit gas, developing the Marcellus shale has increased the total wastewater generated in the region by approximately 570% since 2004, overwhelming current wastewater disposal infrastructure capacity.

Abstract:
Produced water from oil and gas development requires management to avoid negative public health effects, particularly those associated with dissolved solids and bromide in drinking water. Rapidly expanding drilling in the Marcellus Shale in Pennsylvania has significantly increased the volume of produced water that must be managed. Produced water management may include treatment followed by surface water discharge, such as at publically owned wastewater treatment plants (POTWs) or centralized brine treatment plants (CWTs). The use of POTWs and CWTs that discharge partially treated produced water has the potential to increase salt loads to surface waters significantly. These loads may cause unacceptably high concentrations of dissolved solids or bromide in source waters, particularly when rivers are at low-flow conditions. The present study evaluates produced water management in Pennsylvania from 2006 through 2011 to determine whether surface water discharges were sufficient to cause salt or bromide loads that would negatively affect drinking water sources. The increase in produced water that occurred in 2008 in Pennsylvania was accompanied by an increase in use of CWTs and POTWs that were exempt from discharge limits on dissolved solids. Estimates of salt loads associated with produced water and with discharges from CWTs and POTWs in 2008 and 2009 indicate that more than 50% of the total dissolved solids in the produced water generated in those years were released to surface water systems. Especially during the low-flow conditions of 2008 and 2009, these loads would be expected to affect drinking water.

Abstract:
The increasing world demand for energy has led to an increase in the exploration and extraction of natural gas, condensate, and oil from unconventional organic-rich shale plays. However, little is known about the quantity, transport, and disposal method of wastes produced during the extraction process. We examined the quantity of waste produced by gas extraction activities from the Marcellus Shale play in Pennsylvania for 2011. The main types of wastes included drilling cuttings and fluids from vertical and horizontal drilling and fluids generated from hydraulic fracturing [i.e., flowback and brine (formation) water]. Most reported drill cuttings (98.4%) were disposed of in landfills, and there was a high amount of interstate (49.2%) and interbasin (36.7%) transport. Drilling fluids were largely reused (70.7%), with little interstate (8.5%) and interbasin (5.8%) transport. Reported flowback water was mostly reused (89.8%) or disposed of in brine or industrial waste treatment plants (8.0%) and largely remained within Pennsylvania (interstate transport was 3.1%) with little interbasin transport (2.9%). Brine water was most often reused (55.7%), followed by disposal in injection wells (26.6%), and then disposed of in brine or industrial waste treatment plants (13.8%). Of the major types of fluid waste, brine water was most often transported to other states (28.2%) and to other basins (9.8%). In 2011, 71.5% of the reported brine water, drilling fluids, and flowback was recycled: 73.1% in the first half and 69.7% in the second half of 2011. Disposal of waste to municipal sewage treatment plants decreased nearly 100% from the first half to second half of 2011. When standardized against the total amount of gas produced, all reported wastes, except flowback sands, were less in the second half than the first half of 2011. Disposal of wastes into injection disposal wells increased 129.2% from the first half to the second half of 2011; other disposal methods decreased. Some issues with data were uncovered during the analytical process (e.g., correct geospatial location of disposal sites and the proper reporting of end use of waste) that obfuscated the analyses; correcting these issues will help future analyses. Environmental Practice 14:1–10 (2012)

Abstract:
In June 2008, 303,000 L of hydrofracturing fluid from a natural gas well were applied to a 0.20-ha area of mixed hardwood forest on the Fernow Experimental Forest, West Virginia. During application, severe damage and mortality of ground vegetation was observed, followed about 10 d later by premature leaf drop by the overstory trees. Two years after fluid application, 56% of the trees within the fluid application area were dead. Ehrh. was the tree species with the highest mortality, and L. was the least affected, although all tree species present on the site showed damage symptoms and mortality. Surface soils (0-10 cm) were sampled in July and October 2008, June and October 2009, and May 2010 on the fluid application area and an adjacent reference area to evaluate the effects of the hydrofracturing fluid on soil chemistry and to attempt to identify the main chemical constituents of the hydrofracturing fluid. Surface soil concentrations of sodium and chloride increased 50-fold as a result of the land application of hydrofracturing fluids and declined over time. Soil acidity in the fluid application area declined with time, perhaps from altered organic matter cycling. This case study identifies the need for further research to help understand the nature and the environmental impacts of hydrofracturing fluids to devise optimal, safe disposal strategies.

Abstract:
Produced water is the largest waste stream generated in oil and gas industries. It is a mixture of different organic and inorganic compounds. Due to the increasing volume of waste all over the world in the current decade, the outcome and effect of discharging produced water on the environment has lately become a significant issue of environmental concern. Produced water is conventionally treated through different physical, chemical, and biological methods. In offshore platforms because of space constraints, compact physical and chemical systems are used. However, current technologies cannot remove small-suspended oil particles and dissolved elements. Besides, many chemical treatments, whose initial and/or running cost are high and produce hazardous sludge. In onshore facilities, biological pretreatment of oily wastewater can be a cost-effective and environmental friendly method. As high salt concentration and variations of influent characteristics have direct influence on the turbidity of the effluent, it is appropriate to incorporate a physical treatment, e.g., membrane to refine the final effluent. For these reasons, major research efforts in the future could focus on the optimization of current technologies and use of combined physico-chemical and/or biological treatment of produced water in order to comply with reuse and discharge limits.