Repository for Oil and Gas Energy Research (ROGER)

Abstract:
Microbial communities associated with produced water from hydraulic fracturing are not well understood, and their deleterious activity can lead to significant increases in production costs and adverse environmental impacts. In this study, we compared the microbial ecology in prefracturing fluids (fracturing source water and fracturing fluid) and produced water at multiple time points from a natural gas well in southwestern Pennsylvania using 16S rRNA gene-based clone libraries, pyrosequencing, and quantitative PCR. The majority of the bacterial community in prefracturing fluids constituted aerobic species affiliated with the class Alphaproteobacteria. However, their relative abundance decreased in produced water with an increase in halotolerant, anaerobic/facultative anaerobic species affiliated with the classes Clostridia, Bacilli, Gammaproteobacteria, Epsilonproteobacteria, Bacteroidia, and Fusobacteria. Produced water collected at the last time point (day 187) consisted almost entirely of sequences similar to Clostridia and showed a decrease in bacterial abundance by 3 orders of magnitude compared to the prefracturing fluids and produced water samplesfrom earlier time points. Geochemical analysis showed that produced water contained higher concentrations of salts and total radioactivity compared to prefracturing fluids. This study provides evidence of long-term subsurface selection of the microbial community introduced through hydraulic fracturing, which may include significant implications for disinfection as well as reuse of produced water in future fracturing operations.

Abstract:
Almost all of the water used for developing Marcellus Shale gas is withdrawn from surface water sources. State environmental and interstate water authorities take different approaches to managing these withdrawals. In the Upper Ohio River Basin, which covers the western third of Pennsylvania, the Pennsylvania Department of Environmental Protection requires that all water sources used for development have an approved water management plan. For surface water sources the plans stipulate the amount and timing of withdrawals from each source as a function of annual streamflow statistics. Neighboring regulatory authorities and some environmental groups now favor the use of monthly streamflow statistics to establish the conditions for water withdrawals. Our analysis indicates that, given the state of flow measurement data in the Upper Ohio River Basin, the annual streamflow statistics are more likely to prevent water withdrawals during the driest times of the year when aquatic ecosystems are most stressed, and to result in fewer and smaller occurrences of computed low-flow ecodeficits.

Abstract:
Natural gas from tight shale formations will provide the United States with a major source of energy over the next several decades. Estimates of gas production from these formations have mainly relied on formulas designed for wells with a different geometry. We consider the simplest model of gas production consistent with the basic physics and geometry of the extraction process. In principle, solutions of the model depend upon many parameters, but in practice and within a given gas field, all but two can be fixed at typical values, leading to a nonlinear diffusion problem we solve exactly with a scaling curve. The scaling curve production rate declines as 1 over the square root of time early on, and it later declines exponentially. This simple model provides a surprisingly accurate description of gas extraction from 8,294 wells in the United States’ oldest shale play, the Barnett Shale. There is good agreement with the scaling theory for 2,057 horizontal wells in which production started to decline exponentially in less than 10 y. The remaining 6,237 horizontal wells in our analysis are too young for us to predict when exponential decline will set in, but the model can nevertheless be used to establish lower and upper bounds on well lifetime. Finally, we obtain upper and lower bounds on the gas that will be produced by the wells in our sample, individually and in total. The estimated ultimate recovery from our sample of 8,294 wells is between 10 and 20 trillion standard cubic feet.

Abstract:

Abstract:

Abstract:
Hydraulic fracturing (fracking) is a technique used to release and promote the extraction of natural gas (including shale gas, tight gas, and coal bed methane) from deep natural gas deposits. Among the German public there is great concern with regard to the potential environmental impacts of fracking including the contamination of ground water, the most important source of drinking water in Germany. In the present article the risks of ground water contamination through fracking are discussed. Due to the present safety requirements and the obligatory geological and hydrogeological scrutiny of the underground, which has to be performed prior to fracking, the risk of ground water contamination by fracking can be regarded as very low. The toxicity of chemical additives of fracking fluids is discussed. It is recommended that in the future environmental impact assessment and approval of fracs should be performed by the mining authorities in close cooperation with the water authorities. Furthermore, it is recommended that hydraulic fracturing in the future should be accompanied by obligatory ground water monitoring.

Abstract:

Abstract:
The study reports data from an economic choice experiment to determine the likely welfare impacts of hydraulic fracturing, in this case using natural gas extracted by hydraulic fracturing for household electricity. Data were collected from an Internet survey of 515 residents of New York State. The welfare analysis indicated that on average households incur a welfare loss from in-state hydraulic fracturing as the source of their electricity. The evidence suggests that households in shale counties bear more costs from HF electricity than households out of shale counties. The average welfare loss is substantive, estimated at 40–46% of average household electric bills in shale counties and 16–20% of bills in counties without shale. The evidence also suggests that relative proximity to HF well sites also increases cost borne by households.

Abstract:
This study examined a two-year period in which natural gas development in the Marcellus Shale region of Pennsylvania expanded rapidly, as did public policy proposals meant to deal with the myriad legal, economic, and environmental issues that accompanied this growth. Focusing on the use of legitimacy strategies during the critical phase of the issue of hydraulic fracturing, the study examined how activists and energy industry advocates argued that different levels of government policy making – local, state, and federal – should be the locus of policy decisions. Both the “fractivists” and the energy industry sought to legitimize state-level legislators and regulators. Activists viewed federal-level intervention as legitimate leverage for their work in the state, while the energy industry saw federal regulators as redundant and restrictive. Finally, while both sides viewed local authorities as legitimate actors, the energy industry sought to limit their ability to act against the development of new wells.

Abstract:
Newly accessible shale deposits and other unconventional sources of natural gas have dramatically increased global gas reserves and are regarded as major future energy sources. Shale gas drilling began in Texas and is expanding throughout the U.S. and globally. In Texas and other regions, large population centers overlie these deposits. As a result, city residents increasingly come into contact with extraction activities. The proximity of drilling activities to residential areas raises a number of concerns, including noise, dust and emissions hazards, public safety, diminished quality of life, and effects on neighborhood aesthetics and property values. Cities in Texas address these concerns through setback ordinances that regulate the distance between gas wells and residences, schools, floodplains, etc. Although the state of Texas permits drilling 200 ft (61 m) from residences, many municipalities in the Dallas–Fort Worth Metroplex (DFW) have established longer setback distances. This paper analyzes the purpose and basis for setback distances among 26 municipalities in DFW. Findings show that there is no uniform setback distance, distances have increased over time, and, rather than technically-based, setbacks are political compromises. For policy makers confronted with urban shale gas drilling, deriving setback distances from advanced emissions monitoring could decrease setback distance ambiguity.

Abstract:
We investigated whether the increase in the US shale gas production changed the structures of the US and Japanese natural gas markets using market data for the period 2002:5–2012:5. Our analysis consists of a structural break test and market integration analysis. The Bai and Perron structural break test detected a break point of natural gas prices and consumption in 2005 as well as other external shocks – Hurricane Katrina and the Lehman Shock – that are irrelevant to shale gas development. We eliminated the impact of these shocks by separating the data set using the breaks identified in our analysis. We found the breaks skewed the estimation; a market linkage existed between the US and Japanese markets in the original data set, while it did not in the separated data. The vector autoregressive (VAR) model also indicated a significant change before and after the break point; the US market had a one-side influence on the Japanese market before 2005, but the influence disappeared after 2005. Our results implied that the shale gas revolution, triggered by the increase in shale gas production in 2005, caused the change in the relationship between the US and Japanese natural gas markets.

Abstract:
Shale gas has gained increasing worldwide attention in the light of the rapid production and significant effects seen in the United States. Using this case as a reference, several countries have taken the first steps to develop their own resources, with Mexico in particular including shale gas in its energy planning priorities and rushing towards its commercial production, although results have still remained elusive. This paper argues that due to the intrinsic complexity embedded in the shale gas development of the United States, its use as a benchmark by Mexico for policy making purposes is misleading, given the challenges in reproducing the same factors of success on the basis of the contextual differences between both countries. The findings presented can ultimately be helpful for other countries looking forward to or in the process of developing their shale gas resources driven by the same reference.

Abstract:
Engineering estimates of methane emissions from natural gas production have led to varied projections of national emissions. This work reports direct measurements of methane emissions at 190 onshore natural gas sites in the United States (150 production sites, 27 well completion flowbacks, 9 well unloadings, and 4 workovers). For well completion flowbacks, which clear fractured wells of liquid to allow gas production, methane emissions ranged from 0.01 Mg to 17 Mg (mean = 1.7 Mg; 95% confidence bounds of 0.67–3.3 Mg), compared with an average of 81 Mg per event in the 2011 EPA national emission inventory from April 2013. Emission factors for pneumatic pumps and controllers as well as equipment leaks were both comparable to and higher than estimates in the national inventory. Overall, if emission factors from this work for completion flowbacks, equipment leaks, and pneumatic pumps and controllers are assumed to be representative of national populations and are used to estimate national emissions, total annual emissions from these source categories are calculated to be 957 Gg of methane (with sampling and measurement uncertainties estimated at ±200 Gg). The estimate for comparable source categories in the EPA national inventory is ∼1,200 Gg. Additional measurements of unloadings and workovers are needed to produce national emission estimates for these source categories. The 957 Gg in emissions for completion flowbacks, pneumatics, and equipment leaks, coupled with EPA national inventory estimates for other categories, leads to an estimated 2,300 Gg of methane emissions from natural gas production (0.42% of gross gas production).

Abstract:
Shale gas production represents a large potential source of natural gas for the nation. The scale and rapid growth in shale gas development underscore the need to better understand its environmental implications, including water consumption. This study estimates the water consumed over the life cycle of conventional and shale gas production, accounting for the different stages of production and for flowback water reuse (in the case of shale gas). This study finds that shale gas consumes more water over its life cycle (13-37 L/GJ) than conventional natural gas consumes (9.3-9.6 L/GJ). However, when used as a transportation fuel, shale gas consumes significantly less water than other transportation fuels. When used for electricity generation, the combustion of shale gas adds incrementally to the overall water consumption compared to conventional natural gas. The impact of fuel production, however, is small relative to that of power plant operations. The type of power plant where the natural gas is utilized is far more important than the source of the natural gas.

Abstract:
The safe disposal of liquid wastes associated with oil and gas production in the United States is a major challenge given their large volumes and typically high levels of contaminants. In Pennsylvania, oil and gas wastewater is sometimes treated at brine treatment facilities and discharged to local streams. This study examined the water quality and isotopic compositions of discharged effluents, surface waters, and stream sediments associated with a treatment facility site in western Pennsylvania. The elevated levels of chloride and bromide, combined with the strontium, radium, oxygen, and hydrogen isotopic compositions of the effluents reflect the composition of Marcellus Shale produced waters. The discharge of the effluent from the treatment facility increased downstream concentrations of chloride and bromide above background levels. Barium and radium were substantially (>90%) reduced in the treated effluents compared to concentrations in Marcellus Shale produced waters. Nonetheless, 226Ra levels in stream sediments (544?8759 Bq/kg) at the point of discharge were ?200 times greater than upstream and background sediments (22?44 Bq/kg) and above radioactive waste disposal threshold regulations, posing potential environmental risks of radium bioaccumulation in localized areas of shale gas wastewater disposal.

Abstract:
Between November 2009 and September 2011 the EarthScope USArray program deployed ∼25 temporary seismograph stations on a 70-km grid in south-central Texas between 27°N–31°N and 96°W–101°W. This area includes the Eagle Ford Shale. For decades this geographic region has produced gas and oil from other strata using conventional methods, but recent developments in hydrofracturing technology has allowed extensive development of natural gas resources from within the Eagle Ford. Our study surveys small-magnitude seismic events and evaluates their correlation with fluid extraction and injection in the Eagle Ford, identifying and locating 62 probable earthquakes, including 58 not reported by the U.S. Geological Survey. The 62 probable earthquakes occur singly or in clusters at 14 foci; of these foci, two were situated near wells injecting recently increased volumes of water; eight were situated near wells extracting recently increased volumes of oil and/or water; and four were not situated near wells reporting significant injection/extraction increases. Thus in this region, while the majority of small earthquakes may be triggered/induced by human activity, they are more often associated with fluid extraction than with injection. We also investigated the M W 4.8 20 October 2011 Fashing earthquake—the largest historically reported earthquake in south-central Texas—that occurred two weeks after the removal of the temporary USArray stations. A field study indicated that the highest-intensity (MMI VI) region was about 10 km south of 2010–2011 foreshock activity, and that there were no high-volume injection wells within 20 km of the MMI V–VI region or the foreshocks. However, the 20 October 2011 earthquake did coincide with a significant increase in oil/water extraction volumes at wells within the MMI V–VI region, and this was also true for previous earthquakes felt at Fashing in 1973 and 1983. In contrast, our study found significant increases in injection prior to an mbLG3.6 20 July 1991 earthquake near Falls City, Texas. Thus the Eagle Ford geographic region, with seismic activity associated both with extraction and injection, appears to be more complex than the Barnett Shale of northeast Texas, where a similar survey found possible correlations only with fluid injection.

Abstract:
Hydraulically fractured shale formations are being developed widely for oil and gas production. They could also represent an attractive repository for permanent geologic carbon sequestration. Shales have a low permeability, but they can adsorb an appreciable amount of CO2 on fracture surfaces. Here, a computational method is proposed for estimating the CO2 sequestration capacity of a fractured shale formation and it is applied to the Marcellus shale in the eastern United States. The model is based on historical and projected CH4 production along with published data and models for CH4/CO2 sorption equilibria and kinetics. The results suggest that the Marcellus shale alone could store between 10.4 and 18.4 Gt of CO2 between now and 2030, which represents more than 50% of total U.S. CO2 emissions from stationary sources over the same period. Other shale formations with comparable pressure?temperature conditions, such as Haynesville and Barnett, could provide significant additional storage capacity. The mass transfer kinetic results indicate that injection of CO2 would proceed several times faster than production of CH4. Additional considerations not included in this model could either reinforce (e.g., leveraging of existing extraction and monitoring infrastructure) or undermine (e.g., leakage or seismicity potential) this approach, but the sequestration capacity estimated here supports continued exploration into this pathway for producing carbon neutral energy.

Abstract:

Abstract:

Abstract:
An analysis of the energy return on investment (EROI) of natural gas obtained from horizontal, hydraulically fractured wells in the Marcellus Shale was conducted using net external energy ratio methodology and available data and estimates of energy inputs and outputs. Used as sources of input data were estimates of carbon dioxide and nitrogen oxides emitted from the gas extraction processes, as well as fuel-use reports from industry and other sources. Estimates of quantities of materials used and the associated embodied energy as well as other energy-using steps were also developed from available data. Total input energy was compared with the energy expected to be made available to end users of the natural gas produced from a typical Marcellus well. The analysis indicates that the EROI of a typical well is likely between 64:1 and 112:1, with a mean of approximately 85:1. This range assumes an estimated ultimate recovery (EUR) of 3.0 billion cubic feet (Bcf) per well. EROI values are directly proportionate to EUR values. If the EUR is greater or lesser than 3 Bcf, the EROI would be proportionately higher or lower. EROI is also sensitive to the energy used or embedded in gathering and transmission pipelines and associated infrastructure and energy used for their construction, energy consumed in well drilling and well completion, and energy used for wastewater treatment.

Abstract:

Abstract:
Comprehensive on-site radiological survey of processed sludge drilled materials extracted from the oil and gas production activities in the Utica and Marcellus Shale in Ohio has been conducted with a shielded isotopic identifier incorporating an advanced patented algorithmic processor to measure low-activity levels in compliance with environmental standards.

Abstract:
The use of high-volume horizontal hydraulic fracturing (fracking) has increased substantially over the past five years in the United States. Use of this drilling technology to extract natural gas from hitherto impermeable shale is expected to increase even more in coming decades. Two institutions, integration contracts and well spacing requirements, evolved to mitigate the common-pool economic wastes associated with conventional oil and gas drilling. U.S. regulators have applied these institutions to fracking. However, shale plays differ geologically from conventional plays and are subject to different extractive technologies. We theorize that the point-source pollution characteristics of conventional drilling allowed integration contracts and well space requirements to minimize local negative environmental externalities as an unintended byproduct of minimizing common-pool economic wastes. The non-point source pollution characteristics of fracking, however, make these institutions insufficient to minimize negative environmental externalities associated with drilling in shale plays, because the economic waste problem is different. If policymakers understand the crucial differences between conventional oil and gas plays and shale plays and the drilling technologies applied to them, they should be better equipped to craft fracking regulatory policies that internalize problematic externalities.

Abstract:
High-volume horizontal hydraulic fracturing, a controversial new mining technique used to drill for shale gas, is being implemented worldwide. Chemicals used in the process are known neurotoxins, carcinogens, and endocrine disruptors. People who live near shale gas drilling sites report symptoms that they attribute to contaminated air and water. When they seek help from clinicians, a diagnosis is often elusive because the chemicals to which the patients have been exposed are a closely guarded trade secret. Many nurses have voiced grave concern about shale gas drilling safety. Full disclosure of the chemicals used in the process is necessary in order for nurses and other health professionals to effectively care for patients. The economic exuberance surrounding natural gas has resulted in insufficient scrutiny into the health implications. Nursing research aimed at determining what effect unconventional drilling has on human health could help fill that gap. Public health nurses using the precautionary principle should advocate for a more concerted transition from fossil fuels to sustainable energy. Any initiation or further expansion of unconventional gas drilling must be preceded by a comprehensive Health Impact Assessment (HIA).

Abstract:
A comprehensive suite of volatile organic compounds (VOCs) was measured at the semirural Boulder Atmospheric Observatory (BAO) in northeast Colorado during the Nitrogen, Aerosol Composition, and Halogens on a Tall Tower (NACHTT) campaign during the winter of 2011. A signature of elevated nonmethane hydrocarbon (NMHC) mixing ratios was observed throughout the campaign. The C2-C5 alkane mixing ratios were an order of magnitude greater than the regional background. Light alkane mixing ratios were similar to those at urban sites impacted by petrochemical industry emissions with ethane and propane reaching maximums of over 100 ppbv. The mean (± standard deviation) calculated total OH reactivity (7.0 ± 5.0 s−1) was also similar to urban sites. Analysis of VOC wind direction dependence, emission ratios with tracer compounds, and vertical profiles up to 250 m implicated regional natural gas production activities as the source of the elevated VOCs to the northeast of BAO and urban combustion emissions as the major VOC source to the south of BAO. Elevated acetonitrile and dimethyl sulfide mixing ratios were also associated with natural gas emissions. Fluxes of natural gas associated NMHCs were determined to estimate regional emission rates which ranged from 40 ± 14 Gg yr−1 for propane to 0.03 ± 0.01 Gg yr−1 for n-nonane. These emissions have the potential to impact downwind air quality as natural gas associated NMHCs comprised ≈24% of the calculated OH reactivity. The measurements described here provide a baseline for determining the efficacy of future policies designed to control emissions from natural gas production activities.

Abstract:
Natural gas has become a leading source of alternative energy with the advent of techniques to economically extract gas reserves from deep shale formations. Here, we present an assessment of private well water quality in aquifers overlying the Barnett Shale formation of North Texas. We evaluated samples from 100 private drinking water wells using analytical chemistry techniques. Analyses revealed that arsenic, selenium, strontium and total dissolved solids (TDS) exceeded the Environmental Protection Agency?s Drinking Water Maximum Contaminant Limit (MCL) in some samples from private water wells located within 3 km of active natural gas wells. Lower levels of arsenic, selenium, strontium, and barium were detected at reference sites outside the Barnett Shale region as well as sites within the Barnett Shale region located more than 3 km from active natural gas wells. Methanol and ethanol were also detected in 29% of samples. Samples exceeding MCL levels were randomly distributed within areas of active natural gas extraction, and the spatial patterns in our data suggest that elevated constituent levels could be due to a variety of factors including mobilization of natural constituents, hydrogeochemical changes from lowering of the water table, or industrial accidents such as faulty gas well casings.

Abstract:
In the rapidly developing shale gas industry, managing produced water is a major challenge for maintaining the profitability of shale gas extraction while protecting public health and the environment. We review the current state of practice for produced water management across the United States and discuss the interrelated regulatory, infrastructure, and economic drivers for produced water reuse. Within this framework, we examine the Marcellus shale play, a region in the eastern United States where produced water is currently reused without desalination. In the Marcellus region, and in other shale plays worldwide with similar constraints, contraction of current reuse opportunities within the shale gas industry and growing restrictions on produced water disposal will provide strong incentives for produced water desalination for reuse outside the industry. The most challenging scenarios for the selection of desalination for reuse over other management strategies will be those involving high-salinity produced water, which must be desalinated with thermal separation processes. We explore desalination technologies for treatment of high-salinity shale gas produced water, and we critically review mechanical vapor compression (MVC), membrane distillation (MD), and forward osmosis (FO) as the technologies best suited for desalination of high-salinity produced water for reuse outside the shale gas industry. The advantages and challenges of applying MVC, MD, and FO technologies to produced water desalination are discussed, and directions for future research and development are identified. We find that desalination for reuse of produced water is technically feasible and can be economically relevant. However, because produced water management is primarily an economic decision, expanding desalination for reuse is dependent on process and material improvements to reduce capital and operating costs.

Abstract:
With the highest shale gas reserves worldwide and huge need for energy, the Chinese government has introduced many incentives to accelerate the development of shale gas, including subsidies and reduction or waiver of the related fees or taxes. However, the challenges posed by a lack of advanced technologies, environmental protection, a shortage of water in quantity and a knowledge of how to develop a good industry–local community relationship are anticipated in the realization of the predicted golden age of the Chinese shale gas industry. Based on the particular situation and available resources in China, and with reference to the experiences in countries with a developed shale gas industry (such as the U.S.A.) and suggestions by the International Energy Agency, recommendations about the choices facing China can be summarized as follows: allowing foreign investors directly to hold exploration and mining rights in shale gas could facilitate the obtainment of advanced technologies; the improvement of the regulatory arrangements related to environmental protection could make developers more responsible; prompting developers to improve their water-use efficiency could help in not worsening the water supply to some extent; and SLO-based mechanism guidance could be helpful in developing a mutual-trust and -benefit relationship between the shale gas industry and the local community.

Abstract:
With the encouragement of shale gas production in the United States, governments have considered a range of legislative and regulatory proposals to manage health and environmental damages that may accompany extraction activities. Exceptions adopted by Congress to major federal environmental legislation have meant that individual US states have deemed it necessary to provide oversight through regulations to protect people and safeguard environmental quality. In responding, states have legal structures under which drilling firms may not need to disclose the toxic substances used in fracturing wells. Yet, with increasing numbers of drilling sites, more people are at risk from accidents and exposure to harmful substances used at fractured wells. To provide for meaningful health and safety protection, governments may need to reevaluate legal provisions offering trade secret protection for toxic substances used in fracturing.

Abstract:
This paper presents a probabilistic decline curve workflow to model shale gas production from the Barnett, Fayetteville, Haynesville, and Woodford shales. Ranges of model input parameters for four gas shales are provided to guide the preparation of uniform and triangle probability distributions. The input parameter ranges represent realistic distributions of model parameters for specific gas shales.

Abstract:
Methane (CH4) emissions from natural gas production are not well quantified and have the potential to offset the climate benefits of natural gas over other fossil fuels. We use atmospheric measurements in a mass balance approach to estimate CH4 emissions of 55 ± 15 × 103 kg h−1 from a natural gas and oil production field in Uintah County, Utah, on 1 day: 3 February 2012. This emission rate corresponds to 6.2%–11.7% (1σ) of average hourly natural gas production in Uintah County in the month of February. This study demonstrates the mass balance technique as a valuable tool for estimating emissions from oil and gas production regions and illustrates the need for further atmospheric measurements to determine the representativeness of our single-day estimate and to better assess inventories of CH4 emissions.

Abstract:
Shale gas is a novel source of fossil fuel which is extracted by induced hydraulic fracturing, or "fracking". This article examines the socio-political dimension of fracking as manifested in the UK press at three key temporal points in the debate on the practice. Three newspaper corpora were analysed qualitatively using Thematic Analysis and Social Representations Theory. Three overarching themes are discussed: "April-May 2011: From Optimism to Scepticism"; "November 2011: (De-)Constructing and Re-Constructing Risk and Danger"; "April 2012: Consolidating Social Representations of Fracking". In this article, we examine the emergence of and inter-relations between competing social representations, discuss the dynamics of threat positioning and show how threat can be re-construed in order to serve particular socio-political ends in the debate on fracking.

Abstract:
Fracking fluids were released into Acorn Fork, KY, a designated Outstanding State Resource Water, and habitat for the threatened Chrosomus cumberlandensis (Blackside Dace). As a result, stream pH dropped to 5.6 and stream conductivity increased to 35,000 µS/cm, and aquatic invertebrates and fish were killed or distressed. The objective of this study was to describe post-fracking water quality in Acorn Fork and evaluate if the changes in water quality could have extirpated Blackside Dace populations. Semotilus atromaculatus (Creek Chub) and Lepomis cyanellus (Green Sunfish) were collected from Acorn Fork a month after fracking in lieu of unavailable Blackside Dace. Tissues were histologically analyzed for indicators of stress and percent of fish with lesions. Fish exposed to affected Acorn Fork waters showed general signs of stress and had a higher incidence of gill lesions than unexposed reference fish. Gill lesions observed were consistent with exposure to low pH and toxic concentrations of heavy metals. Gill uptake of aluminum and iron was demonstrated at sites with correspondingly high concentrations of these metals. The abrupt and persistent changes in post-fracking water quality resulted in toxic conditions that could have been deleterious to Blackside Dace health and survival.

Abstract:
This paper aims to quantitatively explore the uncertainty around the global potential of shale gas development and its possible impacts, using a multi-regional energy system model, TIAM (TIMES Integrated Assessment Model). Starting from the premise that shale gas resource size and production cost are two key preconditions for its development, our scenario analysis reveals the way these and other variables interact with the global energy system, impacting on the regional distribution of gas production, interregional gas trade, demand and prices. The analysis shows how the reciprocal effects of substitutions on both the supply and demand-side play an important role in constraining or enabling the penetration of shale gas into the energy mix. Moreover, we systematically demonstrate that the global potential for shale gas development is contingent on a large number of intervening variables that manifest themselves in different ways across regionally-distinct energy systems. A simple theoretical model is derived from the results of the scenario analysis. Its purpose is to simplify and explain the complex behaviour of the system, by illustrating the chain of actions and feedbacks induced by different shale gas economics, their magnitude, their relative importance, and the necessary conditions for the global potential to be realised.

Abstract:
Gaining streams can provide an integrated signal of relatively large groundwater capture areas. In contrast to the point-specific nature of monitoring wells, gaining streams coalesce multiple flow paths. Impacts on groundwater quality from unconventional gas development may be evaluated at the watershed scale by the sampling of dissolved methane (CH4) along such streams. This paper describes a method for using stream CH4 concentrations, along with measurements of groundwater inflow and gas transfer velocity interpreted by 1-D stream transport modeling, to determine groundwater methane fluxes. While dissolved ionic tracers remain in the stream for long distances, the persistence of methane is not well documented. To test this method and evaluate CH4 persistence in a stream, a combined bromide (Br) and CH4 tracer injection was conducted on Nine-Mile Creek, a gaining stream in a gas development area in central Utah. A 35% gain in streamflow was determined from dilution of the Br tracer. The injected CH4 resulted in a fivefold increase in stream CH4 immediately below the injection site. CH4 and δ13CCH4 sampling showed it was not immediately lost to the atmosphere, but remained in the stream for more than 2000 m. A 1-D stream transport model simulating the decline in CH4 yielded an apparent gas transfer velocity of 4.5 m/d, describing the rate of loss to the atmosphere (possibly including some microbial consumption). The transport model was then calibrated to background stream CH4 in Nine-Mile Creek (prior to CH4 injection) in order to evaluate groundwater CH4 contributions. The total estimated CH4 load discharging to the stream along the study reach was 190 g/d, although using geochemical fingerprinting to determine its source was beyond the scope of the current study. This demonstrates the utility of stream-gas sampling as a reconnaissance tool for evaluating both natural and anthropogenic CH4 leakage from gas reservoirs into groundwater and surface water.

Abstract:

Abstract:
Abstract Exploration of unconventional natural gas reservoirs such as impermeable shale basins through the use of horizontal drilling and hydraulic fracturing has changed the energy landscape in the USA providing a vast new energy source. The accelerated production of natural gas has triggered a debate concerning the safety and possible environmental impacts of these operations. This study investigates one of the critical aspects of the environmental effects; the possible degradation of water quality in shallow aquifers overlying producing shale formations. The geochemistry of domestic groundwater wells was investigated in aquifers overlying the Fayetteville Shale in north-central Arkansas, where approximately 4000 wells have been drilled since 2004 to extract unconventional natural gas. Monitoring was performed on 127 drinking water wells and the geochemistry of major ions, trace metals, CH4 gas content and its C isotopes (δ13CCH4), and select isotope tracers (δ11B, 87Sr/86Sr, δ2H, δ18O, δ13CDIC) compared to the composition of flowback-water samples directly from Fayetteville Shale gas wells. Dissolved CH4 was detected in 63% of the drinking-water wells (32 of 51 samples), but only six wells exceeded concentrations of 0.5 mg CH4/L. The δ13CCH4 of dissolved CH4 ranged from −42.3‰ to −74.7‰, with the most negative values characteristic of a biogenic source also associated with the highest observed CH4 concentrations, with a possible minor contribution of trace amounts of thermogenic CH4. The majority of these values are distinct from the reported thermogenic composition of the Fayetteville Shale gas (δ13CCH4 = −35.4‰ to −41.9‰). Based on major element chemistry, four shallow groundwater types were identified: (1) low (<100 mg/L) total dissolved solids (TDS), (2) TDS > 100 mg/L and Ca–HCO3 dominated, (3) TDS > 100 mg/L and Na–HCO3 dominated, and (4) slightly saline groundwater with TDS > 100 mg/L and Cl > 20 mg/L with elevated Br/Cl ratios (>0.001). The Sr (87Sr/86Sr = 0.7097–0.7166), C (δ13CDIC = −21.3‰ to −4.7‰), and B (δ11B = 3.9–32.9‰) isotopes clearly reflect water–rock interactions within the aquifer rocks, while the stable O and H isotopic composition mimics the local meteoric water composition. Overall, there was a geochemical gradient from low-mineralized recharge water to more evolved Ca–HCO3, and higher-mineralized Na–HCO3 composition generated by a combination of carbonate dissolution, silicate weathering, and reverse base-exchange reactions. The chemical and isotopic compositions of the bulk shallow groundwater samples were distinct from the Na–Cl type Fayetteville flowback/produced waters (TDS ∼10,000–20,000 mg/L). Yet, the high Br/Cl variations in a small subset of saline shallow groundwater suggest that they were derived from dilution of saline water similar to the brine in the Fayetteville Shale. Nonetheless, no spatial relationship was found between CH4 and salinity occurrences in shallow drinking water wells with proximity to shale-gas drilling sites. The integration of multiple geochemical and isotopic proxies shows no direct evidence of contamination in shallow drinking-water aquifers associated with natural gas extraction from the Fayetteville Shale.

Abstract:
We compile published examples of induced earthquakes that have occurred since 1929 that have magnitudes equal to or greater than 1.0. Of the 198 possible examples, magnitudes range up to 7.9. The potential causes and magnitudes are (a) mining (M 1.6–5.6); (b) oil and gas field depletion (M 1.0–7.3); (c) water injection for secondary oil recovery (M 1.9–5.1); (d) reservoir impoundment (M 2.0–7.9); (e) waste disposal (M 2.0–5.3); (f) academic research boreholes investigating induced seismicity and stress (M 2.8–3.1); (g) solution mining (M 1.0–5.2); (h) geothermal operations (M 1.0–4.6) and (i) hydraulic fracturing for recovery of gas and oil from low-permeability sedimentary rocks (M 1.0–3.8). Reactivation of faults and resultant seismicity occurs due to a reduction in effective stress on fault planes. Hydraulic fracturing operations can trigger seismicity because it can cause an increase in the fluid pressure in a fault zone. Based upon the research compiled here we propose that this could occur by three mechanisms. Firstly, fracturing fluid or displaced pore fluid could enter the fault. Secondly, there may be direct connection with the hydraulic fractures and a fluid pressure pulse could be transmitted to the fault. Lastly, due to poroelastic properties of rock, deformation or ‘inflation’ due to hydraulic fracturing could increase fluid pressure in the fault or in fractures connected to the fault. The following pathways for fluid or a fluid pressure pulse are proposed: (a) directly from the wellbore; (b) through new, stimulated hydraulic fractures; (c) through pre-existing fractures and minor faults; or (d) through the pore network of permeable beds or along bedding planes. The reactivated fault could be intersected by the wellbore or it could be 10s to 100s of metres from it. We propose these mechanisms have been responsible for the three known examples of felt seismicity that are probably induced by hydraulic fracturing. These are in the USA, Canada and the UK. The largest such earthquake was M 3.8 and was in the Horn River Basin, Canada. To date, hydraulic fracturing has been a relatively benign mechanism compared to other anthropogenic triggers, probably because of the low volumes of fluid and short pumping times used in hydraulic fracturing operations. These data and analysis should help provide useful context and inform the current debate surrounding hydraulic fracturing technology.

Abstract:
Various analytical, semi-analytical, and empirical models have been proposed to characterize rate and pressure behavior as a function of time in tight gas and shale gas systems featuring horizontal wells with multiple hydraulic fractures. Despite a few analytical models, as well as a small number of published numerical studies, there is currently little consensus regarding the large-scale flow behavior over time in such systems, particularly regarding the dominant flow regimes and whether or not reservoir properties or volumes can be estimated from well performance data. We constructed a fit-for-purpose numerical simulator which accounts for a variety of production features pertinent to these systems—specifically ultra-tight matrix permeability, hydraulically fractured horizontal wells with induced fractures of various configurations, multiple porosity and permeability fields, and desorption. These features cover the production mechanisms which are currently believed to be most relevant in tight gas and shale gas systems. We employ the numerical simulator to examine various tight gas and shale gas systems and to identify and illustrate the various flow regimes which progressively occur over time. We perform this study at fine grid discretization on the order of 1 mm near fractures to accurately capture flow effects at all time periods. We visualize the flow regimes using specialized plots of rate and pressure functions, as well as maps of pressure and sorption distributions. We use pressure maps to visualize the various flow regimes and their transitions in tight gas systems. In a typical tight gas system, we illustrate the initial linear flow into the hydraulic fractures (i.e., formation linear flow), transitioning to compound formation linear flow, and eventually transforming into elliptical flow. We explore variations of possible shale gas system models. Based on diffusive flow (with and without desorption), we show that due to the extremely low permeability of shale matrix (a few nanodarcies), the flow behavior is dominated by the extent of and configuration of the fractures. This work expands our understanding of flow behavior in tight gas and shale gas systems, where such an understanding may ultimately be used to estimate reservoir properties and reserves in these types of reservoirs.

Abstract:

Abstract:
Unconventional natural gas extraction from tight sandstones, shales, and some coal-beds is typically accomplished by horizontal drilling and hydraulic fracturing that is necessary for economic development of these new hydrocarbon resources. Concerns have been raised regarding the potential for contamination of shallow groundwater by stray gases, formation waters, and fracturing chemicals associated with unconventional gas exploration. A lack of sound scientific hydrogeological field observations and a scarcity of published peer-reviewed articles on the effects of both conventional and unconventional oil and gas activities on shallow groundwater make it difficult to address these issues. Here, we discuss several case studies related to both conventional and unconventional oil and gas activities illustrating how under some circumstances stray or fugitive gas from deep gas-rich formations has migrated from the subsurface into shallow aquifers and how it has affected groundwater quality. Examples include impacts of uncemented well annuli in areas of historic drilling operations, effects related to poor cement bonding in both new and old hydrocarbon wells, and ineffective cementing practices. We also summarize studies describing how structural features influence the role of natural and induced fractures as contaminant fluid migration pathways. On the basis of these studies, we identify two areas where field-focused research is urgently needed to fill current science gaps related to unconventional gas extraction: (1) baseline geochemical mapping (with time series sampling from a sufficient network of groundwater monitoring wells) and (2) field testing of potential mechanisms and pathways by which hydrocarbon gases, reservoir fluids, and fracturing chemicals might potentially invade and contaminate useable groundwater.

Abstract:
The widespread use of hydraulic fracturing (HF) has raised concerns about potential upward migration of HF fluid and brine via induced fractures and faults. We developed a relationship that predicts maximum fracture height as a function of HF fluid volume. These predictions generally bound the vertical extent of microseismicity from over 12,000 HF stimulations across North America. All microseismic events were less than 600 m above well perforations, although most were much closer. Areas of shear displacement (including faults) estimated from microseismic data were comparatively small (radii on the order of 10 m or less). These findings suggest that fracture heights are limited by HF fluid volume regardless of whether the fluid interacts with faults. Direct hydraulic communication between tight formations and shallow groundwater via induced fractures and faults is not a realistic expectation based on the limitations on fracture height growth and potential fault slip.

Abstract:
Movers and Shakers We tend to view earthquakes as unpredictable phenomena caused by naturally shifting stresses in Earth's crust. In reality, however, a range of human activity can also induce earthquakes. Ellsworth (p. 10.1126/science.1225942) reviews the current understanding of the causes and mechanics of earthquakes caused by human activity and the means to decrease their associated risk. Notable examples include injection of wastewater into deep formations and emerging technologies related to oil and gas recovery, including hydraulic fracturing. In addition to directly causing increased local seismic activity, activities such as deep fluid injection may have other ramifications related to earthquake occurrence. Van der Elst et al. (p. 164; see the news story by Kerr) demonstrate that in the midwestern United States, some areas with increased human-induced seismicity are also more prone to further earthquakes triggered by the seismic waves from large, remote earthquakes. Improved seismic monitoring and injection data near deep disposal sites will help to identify regions prone to remote triggering and, more broadly, suggest times when activities should, at least temporarily, be put on hold. A recent dramatic increase in seismicity in the midwestern United States may be related to increases in deep wastewater injection. Here, we demonstrate that areas with suspected anthropogenic earthquakes are also more susceptible to earthquake-triggering from natural transient stresses generated by the seismic waves of large remote earthquakes. Enhanced triggering susceptibility suggests the presence of critically loaded faults and potentially high fluid pressures. Sensitivity to remote triggering is most clearly seen in sites with a long delay between the start of injection and the onset of seismicity and in regions that went on to host moderate magnitude earthquakes within 6 to 20 months. Triggering in induced seismic zones could therefore be an indicator that fluid injection has brought the fault system to a critical state. Wastewater injected deep underground can make some faults more susceptible to triggering by large remote earthquakes. Wastewater injected deep underground can make some faults more susceptible to triggering by large remote earthquakes.

Abstract:
Earthquakes in unusual locations have become an important topic of discussion in both North America and Europe, owing to the concern that industrial activity could cause damaging earthquakes. It has long been understood that earthquakes can be induced by impoundment of reservoirs, surface and underground mining, withdrawal of fluids and gas from the subsurface, and injection of fluids into underground formations. Injection-induced earthquakes have, in particular, become a focus of discussion as the application of hydraulic fracturing to tight shale formations is enabling the production of oil and gas from previously unproductive formations. Earthquakes can be induced as part of the process to stimulate the production from tight shale formations, or by disposal of wastewater associated with stimulation and production. Here, I review recent seismic activity that may be associated with industrial activity, with a focus on the disposal of wastewater by injection in deep wells; assess the scientific understanding of induced earthquakes; and discuss the key scientific challenges to be met for assessing this hazard.

Abstract:

Abstract:
Horizontal drilling and hydraulic fracturing are transforming energy production, but their potential environmental effects remain controversial. We analyzed 141 drinking water wells across the Appalachian Plateaus physiographic province of northeastern Pennsylvania, examining natural gas concentrations and isotopic signatures with proximity to shale gas wells. Methane was detected in 82% of drinking water samples, with average concentrations six times higher for homes <1 km from natural gas wells (P = 0.0006). Ethane was 23 times higher in homes <1 km from gas wells (P = 0.0013); propane was detected in 10 water wells, all within approximately 1 km distance (P = 0.01). Of three factors previously proposed to influence gas concentrations in shallow groundwater (distances to gas wells, valley bottoms, and the Appalachian Structural Front, a proxy for tectonic deformation), distance to gas wells was highly significant for methane concentrations (P = 0.007; multiple regression), whereas distances to valley bottoms and the Appalachian Structural Front were not significant (P = 0.27 and P = 0.11, respectively). Distance to gas wells was also the most significant factor for Pearson and Spearman correlation analyses (P < 0.01). For ethane concentrations, distance to gas wells was the only statistically significant factor (P < 0.005). Isotopic signatures (δ13C-CH4, δ13C-C2H6, and δ2H-CH4), hydrocarbon ratios (methane to ethane and propane), and the ratio of the noble gas 4He to CH4 in groundwater were characteristic of a thermally postmature Marcellus-like source in some cases. Overall, our data suggest that some homeowners living <1 km from gas wells have drinking water contaminated with stray gases.

Abstract:
Brines generated from oil and natural gas production, including flowback water and produced water from hydraulic fracturing of shale gas, may contain elevated concentrations of bromide (similar to 1 g/L). Bromide is a broad concern due to the potential for forming brominated disinfection byproducts (DBPs) during drinking water treatment. Conventional treatment processes for bromide removal is costly and not specific. Selective bromide removal is technically challenging due to the presence of other ions in the brine, especially chloride as high as 30-200 g/L. This study evaluates the ability of solid graphite electrodes to selectively oxidize bromide to bromine in flowback water and produced water from a shale gas operation in Southwestern PA. The bromine can then be outgassed from the solution and recovered, as a process well understood in the bromine industry. This study revealed that bromide may be selectively and rapidly removed from oil and gas brines (similar to 10 h(-1) m(-2) for produced water and similar to 60 h(-1) m(-2) for flowback water). The electrolysis occurs with a current efficiency between 60 and 90%, and the estimated energy cost is similar to 6 kJ/g Br. These data are similar to those for the chlor-alkali process that is commonly used for chlorine gas and sodium hydroxide production. The results demonstrate that bromide may be selectively removed from oil and gas brines to create an opportunity for environmental protection and resource recovery. (C) 2013 Elsevier Ltd. All rights reserved.

Abstract:
This report describes a previously uncharacterized occupational health hazard: work crew exposures to respirable crystalline silica during hydraulic fracturing. Hydraulic fracturing involves high pressure injection of large volumes of water and sand, and smaller quantities of well treatment chemicals, into a gas or oil well to fracture shale or other rock formations, allowing more efficient recovery of hydrocarbons from a petroleum-bearing reservoir. Crystalline silica (“frac sand”) is commonly used as a proppant to hold open cracks and fissures created by hydraulic pressure. Each stage of the process requires hundreds of thousands of pounds of quartz-containing sand; millions of pounds may be needed for all zones of a well. Mechanical handling of frac sand creates respirable crystalline silica dust, a potential exposure hazard for workers. Researchers at the National Institute for Occupational Safety and Health collected 111 personal breathing zone samples at 11 sites in five states to evaluate worker exposures to respirable crystalline silica during hydraulic fracturing. At each of the 11 sites, full-shift samples exceeded occupational health criteria (e.g., the Occupational Safety and Health Administration calculated permissible exposure limit, the NIOSH recommended exposure limit, or the ACGIH threshold limit value), in some cases, by 10 or more times the occupational health criteria. Based on these evaluations, an occupational health hazard was determined to exist for workplace exposures to crystalline silica. Seven points of dust generation were identified, including sand handling machinery and dust generated from the work site itself. Recommendations to control exposures include product substitution (when feasible), engineering controls or modifications to sand handling machinery, administrative controls, and use of personal protective equipment. To our knowledge, this represents the first systematic study of work crew exposures to crystalline silica during hydraulic fracturing. Companies that conduct hydraulic fracturing using silica sand should evaluate their operations to determine the potential for worker exposure to respirable crystalline silica and implement controls as necessary to protect workers. [Supplementary materials are available for this article. Go to the publisher's online edition of Journal of Occupational and Environmental Hygiene for the following free supplemental resource: a file containing controls and recommendations to limit worker exposures to respirable crystalline silica at hydraulic fracturing work sites.]

Abstract:

Abstract:
Over 109 small earthquakes (Mw 0.4–3.9) were detected during January 2011 to February 2012 in the Youngstown, Ohio area, where there were no known earthquakes in the past. These shocks were close to a deep fluid injection well. The 14 month seismicity included six felt earthquakes and culminated with a Mw 3.9 shock on 31 December 2011. Among the 109 shocks, 12 events greater than Mw 1.8 were detected by regional network and accurately relocated, whereas 97 small earthquakes (0.4 < Mw < 1.8) were detected by the waveform correlation detector. Accurately located earthquakes were along a subsurface fault trending ENE-WSW—consistent with the focal mechanism of the main shock and occurred at depths 3.5–4.0 km in the Precambrian basement. We conclude that the recent earthquakes in Youngstown, Ohio were induced by the fluid injection at a deep injection well due to increased pore pressure along the preexisting subsurface faults located close to the wellbore. We found that the seismicity initiated at the eastern end of the subsurface fault—close to the injection point, and migrated toward the west—away from the wellbore, indicating that the expanding high fluid pressure front increased the pore pressure along its path and progressively triggered the earthquakes. We observe that several periods of quiescence of seismicity follow the minima in injection volumes and pressure, which may indicate that the earthquakes were directly caused by the pressure buildup and stopped when pressure dropped.