Repository for Oil and Gas Energy Research (ROGER)

Abstract:
Climate change, the imbalance between China's domestic energy supply and demand, and the success of the shale gas revolution in the United States have been the main motivators for China to actively issue shale gas development policies and explore its own path on this industry. This paper estimates three indicators of economic development: regional GDP, employment level, and the housing price index by using data from China's largest shale gas region, the Fuling District in Chongqing (a municipality in China). The analysis uses a Synthetic Control Method (SCM) model based on data from Fuling itself and other 34 counties of the Chongqing municipality over the period from 2005 to 2018. The results demonstrate that shale gas development has a significant positive effect on both regional GDP and employment level, with average impact growth rates respectively of 9.8% and 12.0%. By contrast, we find an insignificant effect of shale gas development on housing prices. These results support the case for further development of shale gas in China. Note that in some areas our results differ from existing literature, providing a reference for further research in this area.

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Produced water (PW) is a hypersaline waste stream generated from the shale oil and gas industry, consisting of numerous anthropogenic and geogenic compounds. Despite prior geochemical characterization, the comprehensive toxicity assessment is lacking for evaluating treatment technologies and the beneficial use of PW. In this study, a suite of in vitro toxicity assays using various aquatic organisms (luminescent bacterium Vibrio fischeri, fish gill cell line RTgill-W1, and microalgae Scenedesmus obliquus) were developed to investigate the toxicological characterizations of PW from the Permian Basin. The exposure to PW, PW inorganic fraction (PW-IF), and PW salt control (PW-SC) at 30– 50% dilutions caused significant toxicological effects in all model species, revealing the high salinity was the foremost toxicological driver in PW. In addition, the toxicity level of PW was usually higher than that of PW-IF, suggesting that organic contaminants might also play a critical role in PW toxicity. When comparing the observed toxicity with associated chemical characterizations in different PW samples, strong correlations were found between them since higher concentrations of contaminants could generally result in higher toxicity towards exposed organisms. Furthermore, the toxicity results from the pretreated PW indicated that those in vitro toxicity assays had different sensitives to the chemical components present in PW. As expected, the combination of multiple pretreatments could lead to a more significant decrease in toxicity compared to the single pretreatment since the mixture of contaminants in PW might exhibit synergistic toxicity. Overall, the current work is expected to enhance our understanding of the potential toxicological impacts of PW to aquatic ecosystems and the relationships between the chemical profiles and observed toxicity in PW, which might be conducive to the establishment of monitoring, remediation, treatment, and reuse protocols for PW.

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Health studies report associations between metrics of residential proximity to unconventional oil and gas (UOG) development and adverse health endpoints. We investigated whether exposure through household groundwater is captured by existing metrics and a newly developed metric incorporating groundwater flow paths. We compared metrics with detection frequencies/concentrations of 64 organic and inorganic UOG-related chemicals/groups in residential groundwater from 255 homes (Pennsylvania n = 94 and Ohio n = 161). Twenty-seven chemicals were detected in ≥20% of water samples at concentrations generally below U.S. Environmental Protection Agency standards. In Pennsylvania, two organic chemicals/groups had reduced odds of detection with increasing distance to the nearest well: 1,2-dichloroethene and benzene (Odds Ratio [OR]: 0.46, 95% confidence interval [CI]: 0.23–0.93) and m- and p-xylene (OR: 0.28, 95% CI: 0.10–0.80); results were consistent across metrics. In Ohio, the odds of detecting toluene increased with increasing distance to the nearest well (OR: 1.48, 95% CI: 1.12–1.95), also consistent across metrics. Correlations between inorganic chemicals and metrics were limited (all |ρ| ≤ 0.28). Limited associations between metrics and chemicals may indicate that UOG-related water contamination occurs rarely/episodically, more complex metrics may be needed to capture drinking water exposure, and/or spatial metrics in health studies may better reflect exposure to other stressors.

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Regulatory agencies routinely assess the presence of stray gas release from unconventional gas wells by sampling for methane in nearby groundwater after the well is drilled or if citizens complain about methane in their water. We studied whether methane concentrations in groundwater naturally vary through time in a shale gas basin where unconventional development and hydraulic fracturing has not yet occurred, to test the assumption that pre-drilling observations of well water quality can be reliable measures for assessing impacts of later gas drilling. We collected groundwater samples from 11 domestic wells in New York monthly for 13 months for methane and ion concentrations in a highly gas productive part of the Appalachian basin where fracking has been banned. Changing methane concentrations correlated with changes in chloride and bromide, indicating changing mixtures of shallow freshwater and deeper formation brine extracted by the wells through time. The hydrogeologic setting of a water well can cause variability in methane concentrations that may mimic stray gas but cannot be attributable to gas drilling. For this reason, before and after testing has limited utility to distinguish impacts of gas drilling from other causes of changing methane concentrations unless that testing includes sampling a comprehensive set of ions multiple times prior to drilling.

Abstract:
Shale and tight gas developments in the Beetaloo (28,000 km2) and Cooper (139,000 km2) basins of Australia are subject to stringent State and Federal Government controls and assessments. Several scientific investigations are ongoing to improve the scientific basis of the risks from unconventional gas developments to water and the environment. In this study a framework was developed to derive estimates of chemical dilution associated with leakage to groundwater from accidental release of chemicals used for shale and tight gas extraction in Australia. The quantitative assessment accounted for key landscape parameters that determine natural attenuation: soil type, depth to groundwater and groundwater velocity. Both basins were discretised into 1000 × 1000 m2 grids for which the unsaturated zone and groundwater dilution factors were derived. Migration of chemicals through deep unsaturated zones was calculated with the HYDRUS-1D simulator, taking account of best-available hydraulic properties from a digital soil database. A three-dimensional analytical solution of the advection–dispersion equation provided estimates of dilution in groundwater after solutes travelled 500 m from the centre (source location) to the edge of every grid cell. The combined vadose zone-groundwater dilution factors were used to determine under which conditions concentrations of hydraulic fracturing chemicals or flowback water accidentally released into the environment would decrease to levels that are no longer considered harmful to the environment. When the method was applied to 39 hydraulic fracturing chemicals scheduled for stimulation of a shale gas well, ecotoxicological risk quotients (RQ) were calculated to indicate which chemicals were of no environmental concern. This work contributes to increasing the efficiency of quantitative impact assessments and provides a framework to develop dedicated monitoring and management practices to support regulation and management of the gas industry in Australia.

Abstract:
Hydraulic fracturing (HF) remains a current global energy policy issue, and understanding risks to drinking water resources from HF chemicals is an important aspect of this topic. The quantity and quality of disclosed HF chemical information are significant barriers for stakeholders attempting to perform systemic environmental and public health research. A repeatable approach for processing HF chemical disclosure data is provided using United States FracFocus data as a case study. We fill research gaps by examining HF chemical trends between 2014 and 2020 and comparing HF chemicals with a list of reference chemicals known or suspected to be in contact (unrelated to HF) with drinking water, food, or cosmetics. In total, 1,244 unique HF chemicals were identified. Compared with EPA's 2016 HF chemical disclosure research, 480 new chemicals are identified, and 318 previously reported chemicals were not observed. The annual unique chemical counts have dropped from 878 to 594 (32.3%) over the research period, while data quality and transparency have increased. Approximately 69.7% of the identified HF ingredients were found in a list of reference chemicals known or suspected to be in contact (unrelated to HF) with drinking water, food, or cosmetics. Chemical differences between production types (gas and oil) and states are also reviewed. Our research reveals that the sociotechnical system surrounding HF is dynamic and moving toward fewer and, in general, safer chemicals, for those that are disclosed. This study highlights opportunities for new and updated systemic research regarding HF chemical hazard dynamics and associated risk to drinking water resources.

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Hydraulic fracturing drilling technology can cause a high risk of surface spill accidents and thus water contamination. Climate change together with the high water demand and rapid increase in industrial and agricultural activities are valued reasons why we should all care about the availability of water resources and protect them from contamination. Hence, the purpose of this study is to estimate the risk associated with a site contaminated with benzene from oil spillage and its potential impact on groundwater. This study focused on investigating the impact of soil variability and water table depth on groundwater contamination. Temperature-dependent parameters, such as soil water content and the diffusion of pollutants, were considered as key input factors for the HYDRUS 1D numerical model to simulate benzene migration through three types of soil (loamy, sandy clay loam, and silt loam) and evaluate its concentration in the water aquifer. The results indicated that an anticipated increase in earth’s average surface temperature by 4 °C due to climate change could lead to a rise in the level of groundwater pollution in the study area by 0.017 mg/L in loamy soil, 0.00046 mg/L in sandy clay loam soil, and 0.00023 mg/L in silt loam soil. It was found that climate change can reduce the amount of benzene absorbed from 10 to 0.07% in loamy soil, 14 to 0.07% in sandy clay loam soil, and 60 to 53% in silt loam soil. The results showed that the soil properties and solute characteristics that depend on the temperature have a major and important role in determining the level of groundwater pollutants.

Abstract:
Background: Unconventional oil and gas development (UOGD) releases chemicals that have been linked to cancer and childhood leukemia. Studies of UOGD exposure and childhood leukemia are extremely limited. Objective: The objective of this study was to evaluate potential associations between residential proximity to UOGD and risk of acute lymphoblastic leukemia (ALL), the most common form of childhood leukemia, in a large regional sample using UOGD-specific metrics, including a novel metric to represent the water pathway. Methods: We conducted a registry-based case–control study of 405 children ages 2–7 y diagnosed with ALL in Pennsylvania between 2009–2017, and 2,080 controls matched on birth year. We used logistic regression to estimate odds ratios (ORs) and 95% confidence intervals (CIs) for the association between residential proximity to UOGD (including a new water pathway-specific proximity metric) and ALL in two exposure windows: a primary window (3 months preconception to 1 y prior to diagnosis/reference date) and a perinatal window (preconception to birth). Results: Children with at least one UOG well within 2km 2 km of their birth residence during the primary window had 1.98 times the odds of developing ALL in comparison with those with no UOG wells [95% confidence interval (CI): 1.06, 3.69]. Children with at least one vs. no UOG wells within 2km 2 km during the perinatal window had 2.80 times the odds of developing ALL (95% CI: 1.11, 7.05). These relationships were slightly attenuated after adjusting for maternal race and socio-economic status [odds ratio (OR) =1.74 = 1.74 (95% CI: 0.93, 3.27) and OR=2.35 OR = 2.35 (95% CI: 0.93, 5.95)], respectively). The ORs produced by models using the water pathway-specific metric were similar in magnitude to the aggregate metric. Discussion: Our study including a novel UOGD metric found UOGD to be a risk factor for childhood ALL. This work adds to mounting evidence of UOGD’s impacts on children’s health, providing additional support for limiting UOGD near residences. https://doi.org/10.1289/EHP11092

Abstract:
Hydraulic fracturing has induced small-to-moderate-size earthquakes around the world. Identifying spatio-temporal evolution of microseismicity is important for understanding the physical processes that control hydraulic fracturing-induced seismicity. In this study, we build an enhanced earthquake catalog from continuous seismic data recorded by 1-year temporary deployment with an automatic procedure and relocate 18,663 earthquakes in the Weiyuan shale gas block in the southern Sichuan Basin, China. Our catalog, with a maximum ML of 3.5, has a completeness magnitude (Mc) of 0.4, which is ∼23 times more events than listed in the standard National Earthquake Data Center (NEDC) of China. Most earthquakes are clustered near hydraulic fracturing wells and delineate many pre-existing faults in the north-south direction. The space-time evolution of microearthquakes indicates fluid diffusion processes as the primary drivers for seismicity in this region. The fast earthquake migration patterns show that permeability within a fault zone could be affected by fault-valve behaviors and enhanced by earthquake rupture process. We find that the Gutenberg-Richter b-values increase systematically with depth, and b-values further away from hydraulic fracturing pads are generally low, especially for three strands with relatively high migration velocities. Our results confirm that earthquake clusters in Weiyuan are induced by hydraulic fracturing and the reactivated faults act as conduit networks for fluid flow, which promote triggering of earthquakes further away from the hydraulic fracturing pad. This study provides additional evidence for hydraulic fracturing-induced earthquake in the southern Sichuan Basin and advances our understanding of injection induced earthquakes.

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Abstract:
We analyze the temporal evolution of the induced seismicity related to hydraulic fracturing activities in the Duvernay Formation, near Fox Creek, Alberta, Canada. For this analysis, we estimate annual Gutenberg-Richter parameters, - and - values, and then calculate the annual likelihood of earthquakes greater than magnitude from 2014 to 2020. The seismic hazard near Fox Creek has consistently decreased since 2015, from a 95% probability of an earthquake greater than magnitude in 2015 to 4% in 2019 and less than 1% probability in 2020. The induced seismicity in Fox Creek is characterized by two actively seismic regions with distinctive features: (a) an Eastern region (∼220 events ) with lower b-values and higher hazard; (b) a Western region (∼210 events ) with higher b-values and lower seismic hazard. In contrast, extensive regions where hydraulic fracturing is performed, particularly East of the seismic cluster, remain non-seismogenic. The overall decreasing seismic hazard, which contrasts with increasing operator activity, can be associated with (a) the intensification of hydraulic fracturing operations toward areas less susceptible to induced seismicity and (b) the reduction of seismic activity in the Eastern region, which exhibits the highest seismic hazard. We also find evidence of a minimum annual injection volume required to trigger induced seismicity in both the Western and Eastern regions. The minimum injection threshold increases over the years, implying increasingly successful mitigation strategies, likely due to regulatory implementations in the area, which has led the operators to exercise precaution in regions with significant seismic hazard and adapt treatment strategies to avoid triggering moderate magnitude size events during hydraulic fracturing stimulations.

Abstract:
Development of the Permian Basin in recent years has disrupted the global trade of oil and gas. As of January 2020, it was producing more than five million barrels of oil and 20 billion cubic feet of gas per day, with the greatest growth coming from the Delaware Basin sub-play. In this investigation, we report the results of a novel process-based life cycle assessment (LCA) of the greenhouse gas (GHG) emissions associated with oil and gas products from the Delaware Basin, employing extensive operational data including direct measurements of methane emissions. We find that if 1% of the gross gas produced is flared, then the upstream carbon intensity of crude oil is 19.5 kg CO2eq per barrel of crude oil - substantially lower than “global average” intensities reported in the literature. Moreover, the carbon intensities of gasoline, diesel and jet fuel refined from Delaware Basin crudes are approximately 10% less than the U.S. EPA and Department of Energy baselines when a 1% flaring rate is achieved. The life cycle GHG reductions are also a consequence of the physical and chemical properties of Delaware Basin crudes relative to the average crude blend for the U.S., resulting in reduced refinery GHG emissions. We also find that life cycle GHG emissions associated with natural gas from the Delaware Basin are similar to those reported for U.S. shale gas.

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The high management cost of wastewater generated during oil and gas production using hydraulic fracturing technology necessitates economically viable alternative technologies for remediation and reuse. In this study, an Oklahoma native microalgae strain, Komvophoron sp., was grown in four different flowback and produced water samples generated during hydraulic fracturing. Biomass production profile and pollutant removal efficiency of the strain were evaluated. The experimental data demonstrated that this strain was able to grow in all wastewater samples examined when suitable light intensity and CO2 flow rate were provided. Biomass productivity of the strain varied from 5.5 to 12 g m−3 day−1 depending on the wastewater sample used in the cultivation experiments. Very high nitrogen and phosphorus removal from the growth medium, up to 99 and 63%, respectively, could be achieved by growing and harvesting algal biomass in the wastewater samples. A mathematical model developed based on pH, light intensity and CO2 enriched air flow rate as system variables well described the experimental biomass productivity and pollutant removal efficiency data. The proposed mathematical model was successfully used to identify sets of operating conditions which would maximize biomass productivity and macronutrient removal efficiencies. Hence, the model developed in this study is a useful tool to assess technical viability and design of an efficient algal wastewater remediation process to reduce the impact of hydraulic fracturing on environment while producing biomass that can be converted to industrial bio-products including biofuels.

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Oil and gas extraction produces air pollutants that are associated with increased risks of hypertension. To date, no study has examined residential proximity to oil and gas extraction and hypertensive conditions during pregnancy. This study quantifies associations between residential proximity to oil and gas development on gestational hypertension and eclampsia.We utilized a population-based retrospective birth cohort in Texas (1996–2009), where mothers reside <10 km from an active or future drilling site (n = 2 845 144.) Using full-address data, we linked each maternal residence at delivery to assign exposure and evaluate this exposure with respect to gestational hypertension and eclampsia. In a difference-in-differences framework, we model the interaction between maternal health before (unexposed) or after (exposed) the start of drilling activity (exposed) and residential proximity near (0–1, >1–2 or >2–3 km) or far (≥3–10 km) from an active or future drilling site.Among pregnant women residing 0–1 km from an active oil or gas extraction site, we estimate 5% increased odds of gestational hypertension [95% confidence interval (CI): 1.00, 1.10] and 26% increased odds of eclampsia (95% CI: 1.05, 1.51) in adjusted models. This association dissipates in the 1- to 3-km buffer zones. In restricted models, we find elevated odds ratios among maternal ages ≤35 years at delivery, maternal non-Hispanic White race, ≥30 lbs gained during pregnancy, nulliparous mothers and maternal educational attainment beyond high school.Living within 1 km of an oil or gas extraction site during pregnancy is associated with increased odds of hypertensive conditions during pregnancy.

Abstract:
Advances in water treatment technologies paired with potential restrictions on oil and gas (O the sole major breakthrough has been in the development of salt-tolerant fracturing chemicals that allow for reuse of produced water for fracking operations. Guided research should assist in the development of fit-for-purpose solutions to maximize the reuse of treated produced water. This is exemplified by the case studies presented here that detail currently operating treatment facilities for reclamation and reuse of produced water.

Abstract:
The effects of salinity shock on the anaerobic treatment of fracturing wastewater regarding chemical oxygen demand (COD) removal performance, sludge characteristics and microbial community were investigated. Results showed COD removal efficiency decreased from 76.0% to 69.1%, 65.6%, 33.7% and 21.9% with the increase of salinity from 2.5 g/L to 10, 15, 25 and 45 g/L, respectively. The cumulative biogas production decreased by 13.8%–81.1% when salinity increased to 15–85 g/L. The increase of salinity led to the decline in particle size of granular sludge, and the activity of granular sludge, including SMA, coenzyme F420 and dehydrogenase, was inhibited significantly. Flow cytometry indicated the percentage of damaged cells in granular sludge gradually increased with the increase of salinity. Sequence analysis illustrated that microbial community structure in anaerobic digestion reactor was influenced by the salinity, high salinity reduced the diversity of archaea and decreased the abundance of methanogens, especially Methanosaeta.

Abstract:
Quantifying impacts of unconventional oil and gas production on water resources and aquatic habitats is critical for developing management approaches for mitigation. The study objective was to evaluate impacts of oil and gas production on groundwater and surface water and assess approaches to reduce these impacts using the Permian Basin as a case study. Water demand for hydraulic fracturing (HF) was compared to water supplies. We also examined contamination from surface spills. Results show that water demand for HF peaked in 2019, representing ~28% of water use in non-mining sectors. Most HF water was sourced from aquifers with ~1100 wells drilled in the Ogallala aquifer in 2019. The State monitoring network did not show regional groundwater depletion but was not sufficiently dense to address local impacts. Groundwater depletion is more critical in the western Delaware Basin within the Permian Basin because groundwater is connected to large flowing springs (e.g. San Solomon Springs) and to the Pecos River which has total dissolved solids ranging from ~3000 to 14,000 mg/L. Most produced water (70–80%) is disposed in shallow geologic units that could result in overpressuring and potential groundwater contamination from leakage through ~70,000 abandoned oil wells, including orphaned wells. While there is little evidence of leakage from abandoned wells, the state monitoring system was not designed to assess leakage from these wells. Oil spill counts totaled ~11,000 in the Permian (2009–2018). Approaches to mitigating adverse impacts on water management include reuse of PW for HF; however, there is an excess of PW in the Delaware Basin. Treatment and reuse in other sectors outside of oil and gas are also possibilities. Data gaps include reporting of water sources for HF, PW quality data required for assessing treatment and reuse, subsurface disposal capacity for accommodating PW, and spills from PW in Texas.

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The effectiveness of oil and gas produced water (OGPW) applied to unpaved roads to reduce particulate matter (PM10) generation has not been well-characterized. Here we quantify the efficacy of OGPW compared to commercial and alternative byproducts as dust suppressants applied to unpaved roads and estimate efficacy of a dust suppressant extrapolated from both lab experiments and published data for OGPW across U.S. states. Both treated and untreated OGPW, simulated brines, and commercial dust suppressants were characterized by major and trace element composition and then applied to road aggregate in the laboratory. PM10 generation after treatment was quantified, both before and after simulated rain events to assess the need for multiple applications. We found the dust suppression efficacy of all OGPW to be less than commercial products and alternative byproducts such as waste soybean oil. In addition, OGPW lost efficacy following simulated rain events, which would require repeated applications of OGPW to maintain dust suppression. The dust suppression efficacy of OGPW can be estimated based on two chemical measurements, the sodium absorption ratio (SAR) and the total dissolved solids (TDS). OGPW with the lowest SAR and highest TDS performed best as dust suppressants while high SAR and lower TDS led to greater dust generation.

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This paper examines public perceptions of shale gas development in China and the United States. Public perceptions are important, as they are known to influence public policy at national and local levels of government in both multi-party and single-party governance systems. Online surveys were conducted in several states/provinces in each country, the US survey in 2014 (N = 2833); the China survey in 2016 (N = 1571). Similar survey instruments were used in both countries.The survey results show that the reported levels of public support for shale gas development among Chinese respondents in select provinces are significantly higher than that among US respondents in the states included in this study. Perceptions of the advantages and disadvantages of shale gas have both similarities and differences. Shale gas is perceived favorably in both samples because it is seen as a way to reduce dependence on foreign energy suppliers and strengthen the economy. The potential environmental advantages appear to be relatively more important to Chinese respondents than to American respondents. The statement “shale gas development is good for the environment because it substitutes dirty energy such as coal and oil” is seen as “Extremely important” by 54.23% of all Chinese respondents but by only 33.75% of American respondents. When it comes to the potential disadvantages of shale gas development, concerns about impacts on drinking water quality are important in both samples. Earthquakes related to shale gas is the second most important concern to Chinese respondents but a lesser concern to US respondents. We argue that the results are consistent with risk experiences, a variety of socio-cultural theories, and differences in media coverage in the two countries. Future work should examine how public perceptions in the two countries change over time, and how the stances of environmental groups, government, and industry may influence public opinion.

Abstract:
Conflicting evidence exists as to whether or not unconventional oil and gas (UOG) development has enhanced methane transport into groundwater aquifers over the past 15 years. In this study, recent groundwater samples were collected from 90 domestic wells and 4 springs in Northeastern Pennsylvania located above the Marcellus Shale after more than a decade of UOG development. No statistically significant correlations were observed between the groundwater methane level and various UOG geospatial metrics, including proximity to UOG wells and well violations, as well as the number of UOG wells and violations within particular radii. The δ13C and methane-to-higher chain hydrocarbon signatures suggested that the elevated methane levels were not attributable to UOG development nor could they be explained by using simple biogenic–thermogenic end-member mixing models. Instead, groundwater methane levels were significantly correlated with geochemical water type and topographical location. Comparing a subset of contemporary methane measurements to their co-located pre-drilling records (n = 64 at 49 distinct locations) did not indicate systematic increases in methane concentration but did reveal several cases of elevated concentration (n = 12) across a spectrum of topographies. Multiple lines of evidence suggested that the high-concentration groundwater methane could have originated from shallow thermogenic methane that migrated upward into groundwater aquifers with Appalachian Basin brine.

Abstract:
Our study goal was to investigate the impact of biocides and nanoparticles (NPs) on the microbial diversity in a hydraulic fracturing impacted stream. Biocides and NPs are known for their antimicrobial properties and controlling microbial growth. Previous work has shown that biocides can alter the microbial community composition of stream water and may select for biocide-resistant bacteria. Additional studies have shown that nanoparticles can also alter microbial community composition. However, previous work has often focused on the response to a single compound. Here we provide a more thorough analysis of the microbial community response to three different biocides and three different nanoparticles. A microcosm-based study was undertaken that exposed stream microbial communities to either biocides or NPs. Our results showed a decrease in bacterial abundance with different types of nanoparticles, but an increase in microbial abundance in biocide-amended treatments. The microbial community composition (MCC) was distinct from the controls in all biocide and NP treatments, which resulted in differentially enriched taxa in the treatments compared to the controls. Our results indicate that NPs slightly altered the MCC compared to the biocide-treated microcosms. After 14 days, the MCC in the nanoparticle-treated conditions was similar to the MCC in the control. Conversely, the MCC in the biocide-treated microcosms was distinct from the controls at day 14 and distinct from all conditions at day 0. This finding may point to the use of NPs as an alternative to biocides in some settings.

Abstract:
Background:  Prenatal exposure to hydraulic fracturing (HF), a chemically intensive oil and gas extraction method, may be associated with adverse birth outcomes, but no health studies have been conducted in California. Methods:  We conducted a retrospective cohort study of 979,961 births to mothers in eight California counties with HF between 2006 and 2015. Exposed individuals had at least 1 well hydraulically fractured within 1 km of their residence during pregnancy; the reference population had no wells within 1 km, but at least one oil/gas well within 10 km. We examined associations between HF and low birth weight (LBW), preterm birth (PTB), small for gestational age birth (SGA), and term birth weight (tBW) using generalized estimating equations and assessing urban-rural effect modification in stratified models. Results:  Fewer than 1% of mothers (N = 1,192) were exposed to HF during pregnancy. Among rural mothers, HF exposure was associated with increased odds of LBW (odds ratio [OR] = 1.74; 95% confidence interval [CI] = 1.10, 2.75), SGA (OR = 1.68; 95% CI = 1.42, 2.27) and PTB (OR = 1.17; 95% CI = 0.64, 2.12), and lower tBW (mean difference: –73 g; 95% CI = –131, –15). Among urban mothers, HF exposure was positively associated with SGA (OR = 1.23; 95% CI = 0.98, 1.55), inversely associated with LBW (OR = 0.83; 95% CI = 0.63, 1.07) and PTB (OR = 0.65; 95% CI = 0.48, 0.87), and not associated with tBW (mean difference: –2 g; 95% CI = –35, 31). Conclusion:  HF proximity was associated with adverse birth outcomes, particularly among rural Californians.

Abstract:
Biocides are applied as chemical additives in hydraulic fracturing fluids to control subsurface microbial activity. When biocides are released into the subsurface, their fate is controlled by sorption to solids and heterogeneous electron transfer (redox) reactions at the mineral–fluid interface. The ability to predict whether produced water may contain unreacted biocides, or biocide–mineral transformation products, is relevant for defining optimal produced water treatment and beneficial use approaches. This article reviews major minerals that may impact biocide sorption and reactivity in the Marcellus Shale, with a specific focus on biocide–mineral interactions. The chemical and physical properties of quartz, illite, chlorite, pyrite, calcite and dolomite are presented and their reactions with organic compounds structurally similar to biocides are identified. Oxygen-containing functional groups are common among organic biocides, where the carbonyl (–C=O) substructure is integrated into many biocides. Cationic surfactant biocides are expected to sorb to every mineral. Clays, because of their negative surface charge and comparatively high surface area, make excellent sorbents of positively charged biocides. Sorption to organic matter is expected to be limited due to the very polar groups found in biocides. Pyrite is most likely to cause transformation of biocides due to its ability to reduce halogenated organic compounds and initiate Fenton-like reactions, which generate non-specific hydroxyl radicals that react with biocides. Carbonate minerals may act as potential chemisorption sites for biocides possessing a carbonyl group adjacent to another electronegative group. However, the rapid dissolution of this mineral limits its persistence at the mineral–fluid interface. These potential sorption versus transformation reactions can be applied to predict biocide fate in unconventional oil and gas reservoirs and, where appropriate, other subsurface reservoirs used for energy resource extraction or storage.

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Low-cost gravity-driven membrane (GDM) filtration has the potential to efficiently manage highly decentralized shale gas wastewater (SGW). In this work, the feasibility of combining low dosage pre-ozonation with the GDM process was evaluated in the treatment of SGW. The results showed that pre-ozonation significantly increased the stable flux (372%) of GDM filtration, while slightly deteriorating the quality of the effluent water in terms of organic content (−14%). These results were mainly attributed to the conversion of macromolecular organics to low-molecular weight fractions by pre-ozonation. Interestingly, pre-ozonation markedly increased the flux (198%) in the first month of operation also for a GDM process added with granular activated carbon (GGDM). Nevertheless, the flux of O3-GGDM systems dropped sharply around the 25th day of operation, which might be due to the rapid accumulation of pollutants in the high flux stage and the formation of a dense fouling layer. Pre-ozonation remarkably influenced the microbial community structure. And O3-GDM systems were characterized by distinct core microorganisms, which might degrade specific organics in SGW. Furthermore, O3-GDM outperformed simple GDM as a pretreatment for RO. These findings can provide valuable references for combining oxidation technologies with the GDM process in treating refractory wastewater.

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With the increasing consumption of energy in the world, shale gas, as a clean, efficient, and unconventional energy source, has been paid more and more attention. However, it should not be ignored that the process of shale gas exploitation will cause serious environmental pollution, especially water resource consumption and pollution. At present, the quantitative research on water resource cost of shale gas exploitation is rare. On the basis of summarizing the water resource consumption, pollution source in shale gas exploitation. This paper takes Chongqing Fuling national shale gas demonstration area as the research object, and cost measurement models are established from three aspects: water resource consumption, human body damage, and water quality decline. This paper innovatively calculates the water consumption cost of shale gas exploitation in Fuling, Chongqing. The calculation results show that the water consumption cost of Fuling shale gas in Chongqing is 93,639 Yuan per well. The research results provide theoretical basis and data support for enterprises to develop shale gas and the Chinese government to formulate shale gas development plan.

Abstract:
We already know that the construction of shale gas extraction infrastructure exacerbates soil erosion in vulnerable areas. We are not clear however, about whether the completed well pads and pipelines continue to influence soil erosion after the construction is completed. We applied high-resolution remote sensing images and DEM data from 2014 and 2017 and the Revised Universal Soil Loss Equation (RUSLE) model to calculate how the layout of the well pads and pipelines in a shale gas development area affected soil erosion. We used Geodetector to analyze the factors that affected the soil erosion intensity around the well pads. The results showed that about 0.02% and 0.12% of the total erosion in the shale gas development zone was directly caused by the completed well pads and pipelines in 2014 and 2017, respectively. Most of the erosion was related to the completed pipelines. The completed shale gas well pads affected the soil erosion intensity up to 90 and 60 m from the pads in 2014 and 2017, respectively. The soil erosion around the completed pipelines was mainly from the soil surface over the pipeline and had little effect on the surroundings. The main influences on the soil erosion intensity at different distances from the well pads were land use and slope, and the interactions between them. We suggest that, when developing new shale gas extraction facilities, gas pipelines should be arranged in gently sloping areas, and vegetation should be planted on the bare soil over the pipelines to reduce soil erosion.

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With unconventional oil and gas booming in commercial development, its inevitable environmental damage has aroused the public’s vigilance. To support the regulation improvement and early-warning system building, it is of great need to learn the regular patterns in recurrent violations both for practitioners and governments. In this respect, we utilized the “Oil and Gas Compliance Report” from the Pennsylvania Department of Environmental Protection from 2000 to 2019, a total of 5737 violation records, to dig out the historical violation patterns. Through LDA (Latent Dirichlet Allocation) analysis combined with the decision tree model, our research attained the following conclusions: first, we find that the LDA themes of violations as “Erosion and sediment” and “Water pollution” are critical factors for “Failed” enforcement results. Therefore, policymakers and practitioners should pay more attention to those two types of accidents. Second, it is noted that counties are also one of the essential features that matter the enforcement results. Third, we need to consider the role of economic punishment dialectically, while it is not a significant feature for successful enforcement results. That is to say, a monetary penalty may not necessarily improve the effectiveness of the company’s measurements.

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Methane, a potent greenhouse gas, is the main component of natural gas. Previous research has identified considerable methane emissions associated with oil and gas production, but estimates of emission trends have been inconsistent, in part due to limited in-situ methane observations spanning multiple years in oil/gas production regions. Here we present a unique analysis of one of the longest-running datasets of in-situ methane observations from an oil/gas production region in Utah’s Uinta Basin. The observations indicate Uinta methane emissions approximately halved between 2015 and 2020, along with declining gas production. As a percentage of gas production, however, emissions remained steady over the same years, at ~ 6–8%, among the highest in the U.S. Addressing methane leaks and recovering more of the economically valuable natural gas is critical, as the U.S. seeks to address climate change through aggressive greenhouse emission reductions.

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Pressure-retarded osmosis (PRO) is a promising membrane technology for harnessing the osmotic energy of saline solutions. PRO is typically considered with seawater/river water pairings however greater energy can be recovered from hypersaline solutions including produced water (PW) from the petroleum industry. One of the major challenges facing the utilization of hypersaline PW is its high fouling propensity on membranes. In this unique experimental evaluation, real PW from different sites was pretreated to varying degrees: i) minimal, ii) intermediate, and iii) extensive. The treated effluent was subsequently used for PRO testing and fouling rates were assessed for different membrane configurations over multiple cycles. Commercial grade flat sheet (FLS) coupons and novel hollow fiber (HF) modules were compared to validate the lower fouling propensity of HF membranes in PRO application. When minimally pretreated PW (10-micron cartridge filtration (CF)) was tested in FLS mode, severe membrane fouling occurred and the PRO flux decreased by 60%. In contrast, HF modules showed <1% flux decrease under both minimal and intermediate pretreatment schemes. Extensive pretreatment (1-micron CF, dissolved air flotation (DAF), powdered activated carbon, and microfiltration) reduced FLS PRO flux decline to <1%. These results confirm that PW can be treated to suitable levels for PRO application to avoid membrane fouling. Further validation of these pretreatment methods requires long term pilot testing and techno-economic assessment.

Abstract:
Skip to Next Section A comprehensive programme of baseline groundwater hydrochemical monitoring has been carried out in connection with the proposed hydraulic fracturing of a 2 to 3 km deep Bowland Shale gas reservoir in borehole KM8 at Kirby Misperton, North Yorkshire, UK. The monitoring infrastructure encompassed: five on-site boreholes with hydraulically open intervals ranging from shallow weathered cover to a c. 200 m deep Corallian limestone aquifer, six off-site wells (hydraulically open in superficial materials and/or Kimmeridge Clay) and four surface water monitoring stations. Groundwater chemistry was high stratified with depth, ranging from slightly acidic, fresh, very hard Ca-HCO3-SO4 waters in shallow weathered cover, to brackish, calcium-depleted, highly alkaline waters in the Corallian aquifer. Dissolved methane was detected in most boreholes, with 10 µg/L being typical of shallow boreholes and around 50 mg/L in the Corallian. Low ethane concentrations and isotopic evidence suggest that the methane was predominantly microbial in origin (carboxylate fermentation at shallow depth, natural methanogenic CO2 reduction at greater depth). Elevated dissolved ethane (20-30 µg/L) was found in one well of intermediate depth, suggesting admixture of a possible thermogenic component, although this could be derived directly from the Kimmeridge Clay penetrated by the well.

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There is public and scientific concern about air, soil and water contamination and possible adverse environmental and human health effects as a result of hydraulic fracturing activities. The use of greener chemicals in fracturing fluid aims to mitigate these effects. This study compares fracturing fluids marketed as either ‘conventional’ or ‘green’, as assessed by their chemical composition and their toxicity in bioassays. Chemical composition was analysed via non-target screening using liquid chromatography - high resolution mass spectrometry, while toxicity was evaluated by the Ames fluctuation test to assess mutagenicity and CALUX reporter gene assays to determine specific toxicity. Overall, the results do not indicate that the ‘green’ fluids are less harmful than the ‘conventional’ ones. First, there is no clear indication that the selected green fluids contain chemicals present at lower concentrations than the selected conventional fluids. Second, the predicted environmental fate of the identified compounds does not seem to be clearly distinct between the ‘green’ and ‘conventional’ fluids, based on the available data for the top five chemicals based on signal intensity that were tentatively identified. Furthermore, Ames fluctuation test results indicate that the green fluids have a similar genotoxic potential than the conventional fluids. Results of the CALUX reporter gene assays add to the evidence that there is no clear difference between the green and conventional fluids. These results do not support the claim that currently available and tested green-labeled fracturing fluids are environmentally more friendly alternatives to conventional fracturing fluids.

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A large amount of shale gas fracturing flowback fluid (FFBF) from the process of shale gas exploitation causes obvious ecological harm to health of soil and water. However, biological hazard of soil microbial populations by fracturing flowback fluid remains rarely reported. In this study, the microbiological compositions were assessed via analyzing diversity of microbial populations. The results showed significant differences between polluted soil by fracturing flowback fluid and unpolluted soil in different pH and temperature conditions. And then, the microbe-index of biological integrity (M-IBI) was used to evaluate the toxicity of the fracturing flowback fluid based on analysis of microbial integrity. The results showed that polluted soil lacks key microbial species known to be beneficial to soil health, including denitrifying bacteria and cellulose-decomposing bacteria, and 35 °C is a critical value for estimating poor and sub-healthy level of damage to microbial integrity by fracturing flowback fluid. Our results provide a valuable reference for the evaluation of soil damage by fracturing flowback fluid.

Abstract:
Environmental justice (EJ) concerns about shale gas have recently emerged. Relatively little is known about the lived experiences and on-the-ground EJ concerns of UK communities facing drilling proposals. We address this knowledge gap through a UK case study of Woodsetts, South Yorkshire, where a prolonged planning process has created anticipatory EJ issues that demonstrate how injustices occur prior to development, creating damaging effects on a community across several years. We find evidence of both well-established and newly emerging distributive, procedural and recognition justice issues, including concerns about the disparate distribution of risks for the most intersectionally-vulnerable residents, a lack of timely access to data and information, and a lack of understanding and recognition of local residents and their place-based concerns. These findings have conceptual implications for future research on perceptions, anticipations and experiences of EJ, as well as practical implications for future energy proposals aimed at meeting net zero emissions.

Abstract:
Hydraulic fracturing wastewater (HFW), a byproduct of hydraulic fracturing oil extraction, contains a complex mixture of oil, aldehydes, and benzene compounds. Efficient and eco-friendly HFW treatment means are critical for the oil extraction industry, particularly in developing countries. In this study, two biological processes namely an anaerobic/anoxic/moving bed biofilm reactor (A2-MBBR) and an A2-MBBR with a microfiltration membrane (A2-MFMBBR) were established, and assessed for the real HFW treatment. Removal efficiencies of chemical oxygen demand (COD) and NH4+-N were over 92% and 95%, respectively, in both processes with a hydraulic retention time of 72 h. The majority of organic compounds in both systems identified by GC–MS were degraded in the anaerobic units. In comparison, A2-MFMBBR demonstrated higher removal efficiencies for oil, total suspended solids, and complex compounds. The average relative abundances of refractory compound degrading bacteria were 43.4% and 51.6% in the A2-MBBR and A2-MFMBBR, respectively, which was consistent with the COD and oil removal, and suggested that the MBR could maintain a high diversity of microorganisms and contribute to deep recalcitrant organics degradation. This study sheds light on the potential of using a compact biological process for the real HFW treatment.

Abstract:
Abstract The resurgence of oil and gas extraction in the Appalachian Basin has resulted in an excess of oil and gas brines in Pennsylvania, West Virginia, and Ohio. Primarily driven by unconventional development, this expansion has also impacted conventional wells and consequently, created economic pressure to develop effective and cheap disposal options. Using brine as a road treatment, directly or as a processed deicer, however, creates substantial concern that naturally occurring radioactive material in the brines can contaminate roads and road-side areas. Current decision making is based on risk exposure scenarios developed by regulatory agencies based on recreational users in rural areas and exposures to drivers during a typical commute. These scenarios are not appropriate for evaluating exposures to residential deicer users or people living near treated streets. More appropriate exposure scenarios were developed in this work and exposures predicted with these models based on laboratory measurements and literature data. Exposure scenarios currently used for regulatory assessment of brine road treatment result in predicted exposures of 0.4-0.6 mrem/year. Residential exposures predicted by the scenarios developed in this work are 4.6 mrem/year. If the maximum range of near-road soil radium concentrations observed in the region is used in this residential scenario (60 pCi/g 226 Ra, 50 pCi/g 228 Ra), residents living near these roads would be exposed to an estimated 296 mrems/year, above regulatory exposure thresholds used in nuclear facility siting assessments. These results underline the urgent need to clarify exposure risks from the use of oil and gas brines as a road treatment, particularly given the existing disparities in the distribution of road impacts across socioeconomic status.

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As hydraulic fracturing (HF) practices keep expanding in China, a comparative understanding of biological characteristics of flowback and produced waters (FPW) and sludge in impoundments for FPW reserve will help propose appropriate treatment strategies. Therefore, in this study, the microbial communities and functions in impoundments that collected wastewaters from dozens of wells were characterized. The results showed that microbial richness and diversity were significantly increased in sludge compared with those in FPW. The vast majority of microorganisms found in FPW and sludge are organic degraders, providing the possibility of using these indigenous microorganisms to biodegrade organic compounds. Our laboratory findings first show that wastewater pretreatment using these microorganisms was effective, and organic compounds in FPW from different shale formations were removed by 35–68% within 72 h in a wide temperature range (8 – 30 ℃). Meanwhile, highly toxic compounds such as phthalate esters (PAEs), polycyclic aromatic hydrocarbons (PAHs), and petroleum hydrocarbons were effectively eliminated in reactors. The main microorganisms, key functional genes, and putative pathways for alkanes, PAHs, and PAEs degradation were also identified.

Abstract:
Revenues from oil and gas development play a key role in the economies of many states in the United States, but there are environmental concerns such as local air and water pollution, land cover changes and fragmentation, and negative effects on wildlife. These concerns were exacerbated as oil and gas production reached historic highs due to the expanded use of hydraulic fracturing technology beginning in the mid-2000s. This paper examines the influence of oil and gas development on breeding bird communities in the High Plains ecoregion of Colorado between 2003 and 2018. Specifically, we investigated whether oil and gas drilling or production affected species richness or evenness of bird communities. Our findings indicate that a decrease in producing well density or the number of producing fracking wells were associated with an increase in evenness of the overall bird community and grassland species richness, but disturbances from well drilling generally did not have a statistically significant influence on bird communities. We also found that a decrease in tree cover was associated with an increase in species richness and evenness of the overall bird community.

Abstract:
Research on hydraulic fracturing has documented disruptive effects on communities, noting parallels with and departures from previous energy “boomtown” studies. Some recent national and regional-scale research utilizes proximity to energy industry activity as a predictor of public opinion and perceived impacts of hydraulic fracturing, but few studies examine the role of proximity at the local scale. The current study focuses on two Pennsylvania communities that experienced a heavy wave of Marcellus Shale development, testing whether proximity to different levels of industry activity predicts the degree of support for and perception of impacts from hydraulic fracturing. Also examined is the effect of perceived exposure to industry activity. The results of this study show that proximity to hydraulic fracturing activity matters, reducing support for hydraulic fracturing and strengthening views of community and environmental impacts. This effect of proximity is, however, indirect, operating through respondents’ perceived exposure to the array of hydraulic fracturing activities that took place in their areas.

Abstract:
For shale gas resevoirs development, many researches focus on how to improve the estimated ultimate recovery (EUR), and ignore the relation of economic benefits and EUR. Therefore, based on the research of EUR evaluation procedure as the basis of economic estimation, the relation of economic benefits and EUR is revealed in detail, and the economy-geology-engineering (EGE) model is creatively built. The results show that six researched wells all have economic benefits: the average EUR is 1.60 × 108 m3, and the after-tax averages of net present value, financial internal rate of return and investment payback period (Pt) are 434.32 × 104 USD, 10.39% and 4.45 years respectively. Combining with the seepage theory and on-site experience, the negative relation of Pt and development degree of free gas is determined. The economic benefits for the unit volume of shale gas are close about 0.03 USD/m3 under the current development technologies. The influence degrees of economic parameters from large to small are gas price, drilling cost, fracturing cost, business cost and subsidy respectively. The proposed EGE model can effectively predict the economic benefits with the complex geology-engineering factors in the Changning block, and the corresponding method can be generalized to more fields.

Abstract:
To date, little research has investigated how public perceptions of policies to ban or restrict fossil-fuel extraction change over time; yet this topic is of crucial importance as countries worldwide seek to transition towards ‘net zero’ economies. This study addresses this gap by focusing on public responses to the 2019 moratorium on shale gas extraction in England, using an analytical framework comprising awareness, interpretations and opinions, and a mixed-method approach combining national survey, social media and local case interviews. Findings show high levels of awareness and support for the moratorium, yet differences between coalitions of interest based on ideology, scale and demographics. Social media analyses reveal a peak in public response across several days during a general election campaign in which different parties took divergent positions on shale gas. Public support for the moratorium – and induced seismicity as the primary reason for its introduction - was evidenced by the national survey, yet coincided with scepticism about its timing, extent and motivation, as indicated by social media activity and local case interviews. For some publics, the moratorium was a ploy to ensure electoral support, embedded in public distrust. This study indicates the merits of a mixed-method approach to understand the psychological and institutional context of public responses to policy change as it unfolds over time, and discusses the longer term implications of politicised attitudes for energy transitions.

Abstract:
Water scarcity is one of the main challenges worldwide that might propose various engineering and economic issues. Petroleum industries have encountered these issues seriously, which required pretreatment facilities before reinjecting the produced water into the production wells. To assure that the treated water has no side effect on the environment, the treatment processes would perform three times by the photo-Fenton flotation method. This paper, it is aimed to calculate the treated water, required water, and saving water for chemically enhanced oil recovery methods (CEOR), hydraulic fracturing (HF), and other service facilities for completion and drilling performances. According to the results of this study, oil-well#3 has the highest water savings among all the wells with the 89% of daily water-saving, and oil-well#4 has the highest water savings among oil wells with the 75% of daily water saving. Consequently, in Sirri oilfield, the water-saving percentage is about 82% and 72%, which indicated that it is required 18%, 28% of the total water volume for implantation of HF process and CEOR methods, respectively. The total annual required water for this oilfield is 4131 MM m3/Day.

Abstract:
Monitoring small magnitude induced seismicity requires a dense network of seismic stations and high-quality recordings in order to precisely determine events’ hypocentral parameters and mechanisms. However, microseismicity (e.g. swarm activity) can also occur in an area where a dense network is unavailable and recordings are limited to a few seismic stations at the surface. In this case, using advanced event detection techniques such as template matching can help to detect small magnitude shallow seismic events and give insights about the ongoing process at the subsurface giving rise to microseismicity. In this paper, we study shallow microseismic events caused by hydrofracking of the PNR-2 well near Blackpool, UK, in 2019 using recordings of a seismic network which was not designed to detect and locate such small events. By utilizing a sparse network of surface stations, small seismic events are detected using template matching technique. In addition, we apply a full-waveform moment tensor inversion to study the focal mechanisms of larger events (ML > 1) and used the double-difference location technique for events with high-quality and similar waveforms to obtain accurate relative locations. During the stimulation period, temporal changes in event detection rate were in agreement with injection times. Focal mechanisms of the events with high-quality recordings at multiple stations indicate a strike-slip mechanism, while a cross-section of 34 relocated events matches the dip angle of the active fault.

Abstract:
Produced water (PW) is the largest waste stream associated with oil and gas (O&G) operations and contains petroleum hydrocarbons, heavy metals, salts, naturally occurring radioactive materials and any remaining chemical additives. In some areas in Wyoming, constructed wetlands (CWs) are used to polish PW downstream of National Pollutant Discharge Elimination System (NPDES) PW release points. In recent years, there has been increased interest in finding lower cost options, such as CWs, for PW treatment. The goal of this study was to understand the efficacy of removal and environmental fate of O&G organic chemical additives in CW systems used to treat PW released for agricultural beneficial reuse. To achieve this goal, we analyzed water and sediment samples for organic O&G chemical additives and conducted 16S rRNA gene sequencing for microbial community characterization on three such systems in Wyoming, USA. Three surfactants (polyethylene glycols, polypropylene glycols, and nonylphenol ethoxylates) and one biocide (alkyldimethylammonium chloride) were detected in all three PW discharges and >94% removal of all species from PW was achieved after treatment in two CWs in series. These O&G extraction additives were detected in all sediment samples collected downstream of PW discharges. Chemical and microbial analyses indicated that sorption and biodegradation were the main attenuation mechanisms for these species. Additionally, all three discharges showed a trend of increasingly diverse, but similar, microbial communities with greater distance from NPDES PW discharge points. Results of this study can be used to inform design and management of constructed wetlands for produced water treatment.

Abstract:
The expansion of petroleum resource development has led to growing concern regarding greenhouse gas emissions from fugitive gas migration, which occurs at some wells due to well integrity failure. In this study, we quantify methane surface expression and emissions resulting from gas migration using a number of complementary techniques, and thereby evaluate surface expression processes as well as the strengths and limitations of the monitoring techniques. Methane emissions were found to be highly localized and variable over time. Injected gas reached the surface via preferential pathways through the soils and also along an installed groundwater monitoring well. Cumulative emissions were estimated from flux chamber measurements to be 3.8–6.5% of the injected gas; whereas eddy covariance (EC) data inferred approximately 26% of the injected gas was released to the atmosphere. Together these methods provide enhanced interpretation of surface expression at the site, advance our understanding on fugitive gas migration from integrity compromised energy wells and provide insights to improve monitoring and detection strategies with a view to reducing future greenhouse gas emissions. Moreover that, up to 75% of fugitive gas released at the site remained in the subsurface, shows that capillary barriers will mitigate greenhouse gas emissions from leaky wells; however, may infer greater potential for impacts on groundwater resources, if present.

Abstract:
Large stores of previously inaccessible hydrocarbons have become available due to the development of hydraulic fracturing technologies. During the hydraulic fracturing process, a mixture of water and proprietary additives is injected into geologic formations to release trapped hydrocarbons. After fracturing, injected water and fluid from the target formation return to the surface as flowback and produced water (FPW), a potentially toxic byproduct of hydraulic fracturing activities. FPW is a complex mixture that contains chemical additives present in the initial injection fluid as well as salts, metals, and a variety of organic compounds. As a result, FPW composition can be highly variable across wells from different geological formations, methods of fracturing and well development, and well age. The present study sought to determine if FPW sourced from four wells (O, P, U, V) located on the same well pad within the Montney Formation have similar levels of acute and chronic toxicity to the freshwater invertebrate, Daphnia magna. Minimal differences in the estimated 48 h LC50 concentrations were observed among the studied wells. Long-term, 21 d exposures to ≤2% FPW revealed differences in the level of lethality between wells, including complete mortality in daphnids exposed to 2% well O by day 9. No sublethal effects were observed as a result of exposure to FPW from wells P, U or V; however, a large impairment of reproductive traits and molting behaviour were detected after exposure to 0.75% well O FPW. These results indicate that FPW sourced from wells on the same well pad cannot be considered the same in terms of chemical composition or toxicity, an important distinction to make for risk assessment practices.

Abstract:
The chemical characteristic of flowback fluid from hydraulic fracturing for shale gas exploration/production in various localizations is presented. The results of statistical analysis have shown that variability in the chemical composition of these fluids is statistically significant and depends on the time difference between fracturing process and flowback sampling as well as sampling spot within the installation for flowback collection. Parameters which depend on sampling schedule (time and spot of sampling) are as follows: electrical conductivity and concentration of ammonia, boron, barium, calcium, lithium, sodium, magnesium, manganese, sodium, strontium, silicate, bromide, and chloride. Independent parameters are pH, total organic carbon (TOC), concentration of potassium, and iron. The ranges of the values of the characteristic parameters were determined, taking into account the representativeness of the samples, supported by statistical tests. The methods for the reuse of flowback fluids in terms of chemical composition are presented.

Abstract:
Background: There is growing concern about the recent increase in oil and gas development using hydraulic fracturing. Studies linking adverse birth outcomes and maternal proximity to hydraulic fracturing wells exist but tend to use individualized maternal and infant data contained in protected health care records. In this study, we extended the findings of these past studies to evaluate if analogous effects detected with individualized data could be detected from non-individualized county-wide aggregated data.Design and Methods: This study used a retrospective cohort of 252,502 birth records from 1999 to 2019 gathered from a subset sample of 5 counties in the state of Colorado where hydraulic fracturing activities were conducted. We used Generalized Linear Models to evaluate the effect of county-wide well density and production data over unidentified birth weight, and prematurity data. Covariates used in the model were county-wide statistics sourced from the US Census.Results: Our modeling approach showed an interesting effect where hydraulic fracturing exposure metrics have a mixed effect directional response. This effect was detected on birth weight when well density, production and their interaction are accounted for. The interaction effect provides an additional interpretation to discrepancies reported previously in the literature. Our approach only detected a positive association to prematurity with increased production.Conclusions: Our findings demonstrate two main points: First, the effect of hydraulic fracturing is detectable by using county-wide unidentified data. Second, the effect of hydraulic fracturing can be complicated by the number of operations and the intensity of the activities in the area.

Abstract:
In many countries, natural gas is perceived more favorably than other fossil fuels. Here, we experimentally test (N = 2931) how perceptions of natural gas vary depending on what it is called. We find that Americans have stronger positive feelings for the term “natural gas” than “natural methane gas” (d = 0.59), “fossil gas” (d = 0.80), “fracked gas” (d = 0.81), “methane” (d = 0.94), and “methane gas” (d = 0.96). Democrats and Republicans both reported more positive views of “natural gas” than “natural methane gas” or “methane [gas].” But the patterns for the two political parties differed for perceptions of “fossil gas” and “fracked gas,” which were both viewed relatively positively by Republicans but negatively by Democrats. Analyses of open-ended word associations found that many participants associated methane with words like “pollution” and “global warming,” whereas they associated natural gas with words like “clean.” The results suggest that the terms used for this fossil fuel have very different meanings among the public, which may affect people's risk perceptions, consumer choices, and support for related policies.

Abstract:
Drawing from hazard and disaster literature, this article advances Freudenburg’s concept of recreancy and Hobfoll’s Conservation of Resources theory in response to calls for more theory development in research on hydraulic fracturing. Respectively, these theoretical frames refer to stress associated with trust in institutional failure to safeguard the wellbeing of society, as well as resource loss, threat of loss, or investment of resources without return or gain. We contribute to the expanding body of knowledge in energy and social science research by investigating risk perceptions of induced seismicity (earthquakes) associated with hydraulic fracturing processes. Using structural equation modeling, we analyze data from a 2018 household telephone survey in two regions of Oklahoma (N = 600). Findings indicate that perceptions of recreancy (β = 0.38), opinion of fracking risks (β = 0.31), and number of earthquakes (β = 0.11) directly affect perceptions of earthquake risk, while political views, economic resource loss and views of fracking benefits are indirectly related to perceptions of earthquake risk.

Abstract:
Background Northeastern British Columbia (Canada) is an area of unconventional natural gas (UNG) exploitation by hydraulic fracturing, which can release several contaminants, including volatile organic compounds (VOCs). To evaluate gestational exposure to contaminants in this region, we undertook the Exposures in the Peace River Valley (EXPERIVA) study. Objectives We aimed to: 1) measure VOCs in residential indoor air and tap water from EXPERIVA participants; 2) compare concentrations with those in the general population and explore differences related to sociodemographic and housing characteristics; and 3) determine associations between VOC concentrations and density/proximity to UNG wells. Methods Eighty-five pregnant women participated. Passive air samplers were analyzed for 47 VOCs, and tap water samples were analyzed for 44 VOCs. VOC concentrations were compared with those from the Canadian Health Measure Survey (CHMS). We assessed the association between different metrics of well density/proximity and indoor air and tap water VOC concentrations using multiple linear regression. Results 40 VOCs were detected in >50% of air samples, whereas only 4 VOCs were detected in >50% of water samples. We observed indoor air concentrations >95th percentile of CHMS in 10–60% of samples for several compounds (acetone, 2-methyl-2-propanol, chloroform, 1,4-dioxane, hexanal, m/p-xylene, o-xylene, styrene, decamethylcyclopentasiloxane, dodecane and decanal). Indoor air levels of chloroform and tap water levels of total trihalomethanes were higher in Indigenous participants compared to non-Indigenous participants. Indoor air levels of chloroform and acetone, and tap water levels of total trihalomethanes were positively associated with UNG wells density and proximity metrics. Indoor air BTEX (benzene, toluene, ethylbenzene, xylenes) levels were positively correlated with well density/proximity metrics. Conclusion Our results suggest higher exposure to certain VOCs in pregnant women living in an area of intense unconventional natural gas exploitation compared with the general Canadian population, and that well density/proximity is associated with increased exposure to certain VOCs.